Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization

Bismuth telluride nanoparticles (NPs) attract attention due to the growth of sensitivity of the Bi2Te3 NPs-containing registrars in the near- and mid-infrared ranges. We describe the synthesis and characterization of these structures and analyze the low-order nonlinear optical properties of the coll...

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Autores principales: Ganeev Rashid A., Popov V. S., Zvyagin A. I., Lavrentyev N. A., Mirofyanchenko A. E., Mirofyanchenko E. V., Shuklov I. A., Ovchinnikov O. V., Ponomarenko V. P., Razumov V. F.
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Publicado: De Gruyter 2021
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spelling oai:doaj.org-article:0b779017123e452d8be8506b3a4ea1182021-12-05T14:10:56ZExfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization2192-861410.1515/nanoph-2021-0335https://doaj.org/article/0b779017123e452d8be8506b3a4ea1182021-09-01T00:00:00Zhttps://doi.org/10.1515/nanoph-2021-0335https://doaj.org/toc/2192-8614Bismuth telluride nanoparticles (NPs) attract attention due to the growth of sensitivity of the Bi2Te3 NPs-containing registrars in the near- and mid-infrared ranges. We describe the synthesis and characterization of these structures and analyze the low-order nonlinear optical properties of the colloidal suspensions and thin films containing Bi2Te3 NPs using 1064 and 532 nm, 10 ns pulses. Colloidal Bi2Te3 NPs demonstrate saturable absorption and positive nonlinear refraction (saturation intensity 7 × 108 W cm−2, nonlinear absorption coefficient β SA = −7 × 10−8 cm W−1, nonlinear refractive index γ = 9 × 10−12 cm2 W−1), while at stronger excitation by 532 nm, 10 ns pulses the reverse saturable absorption dominates over other nonlinear optical processes. We achieved significant growth of the nonlinear optical parameters of the thin films containing these NPs (film thickness l = 60 nm, β SA = −1.2 × 10−4 cm W−1, γ = 5 × 10−7 cm2 W−1 in the case of 532 nm probe radiation and β = −5 × 10−5 cm W−1, γ = 6 × 10−8 cm2 W−1 in the case of 1064 nm probe radiation) compared with colloidal Bi2Te3 NPs and discuss the observed peculiarities of the nonlinear response of Bi2Te3 nanostructures.Ganeev Rashid A.Popov V. S.Zvyagin A. I.Lavrentyev N. A.Mirofyanchenko A. E.Mirofyanchenko E. V.Shuklov I. A.Ovchinnikov O. V.Ponomarenko V. P.Razumov V. F.De Gruyterarticlebismuth telluride nanoparticlesnonlinear refractionreverse saturable absorptionsaturable absorptionsynthesisPhysicsQC1-999ENNanophotonics, Vol 10, Iss 15, Pp 3857-3870 (2021)
institution DOAJ
collection DOAJ
language EN
topic bismuth telluride nanoparticles
nonlinear refraction
reverse saturable absorption
saturable absorption
synthesis
Physics
QC1-999
spellingShingle bismuth telluride nanoparticles
nonlinear refraction
reverse saturable absorption
saturable absorption
synthesis
Physics
QC1-999
Ganeev Rashid A.
Popov V. S.
Zvyagin A. I.
Lavrentyev N. A.
Mirofyanchenko A. E.
Mirofyanchenko E. V.
Shuklov I. A.
Ovchinnikov O. V.
Ponomarenko V. P.
Razumov V. F.
Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
description Bismuth telluride nanoparticles (NPs) attract attention due to the growth of sensitivity of the Bi2Te3 NPs-containing registrars in the near- and mid-infrared ranges. We describe the synthesis and characterization of these structures and analyze the low-order nonlinear optical properties of the colloidal suspensions and thin films containing Bi2Te3 NPs using 1064 and 532 nm, 10 ns pulses. Colloidal Bi2Te3 NPs demonstrate saturable absorption and positive nonlinear refraction (saturation intensity 7 × 108 W cm−2, nonlinear absorption coefficient β SA = −7 × 10−8 cm W−1, nonlinear refractive index γ = 9 × 10−12 cm2 W−1), while at stronger excitation by 532 nm, 10 ns pulses the reverse saturable absorption dominates over other nonlinear optical processes. We achieved significant growth of the nonlinear optical parameters of the thin films containing these NPs (film thickness l = 60 nm, β SA = −1.2 × 10−4 cm W−1, γ = 5 × 10−7 cm2 W−1 in the case of 532 nm probe radiation and β = −5 × 10−5 cm W−1, γ = 6 × 10−8 cm2 W−1 in the case of 1064 nm probe radiation) compared with colloidal Bi2Te3 NPs and discuss the observed peculiarities of the nonlinear response of Bi2Te3 nanostructures.
format article
author Ganeev Rashid A.
Popov V. S.
Zvyagin A. I.
Lavrentyev N. A.
Mirofyanchenko A. E.
Mirofyanchenko E. V.
Shuklov I. A.
Ovchinnikov O. V.
Ponomarenko V. P.
Razumov V. F.
author_facet Ganeev Rashid A.
Popov V. S.
Zvyagin A. I.
Lavrentyev N. A.
Mirofyanchenko A. E.
Mirofyanchenko E. V.
Shuklov I. A.
Ovchinnikov O. V.
Ponomarenko V. P.
Razumov V. F.
author_sort Ganeev Rashid A.
title Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
title_short Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
title_full Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
title_fullStr Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
title_full_unstemmed Exfoliated Bi2Te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
title_sort exfoliated bi2te3 nanoparticle suspensions and films: morphological and nonlinear optical characterization
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/0b779017123e452d8be8506b3a4ea118
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