Design, Fabrication and Characterization of Pressure-Responsive Films Based on The Orientation Dependence of Plasmonic Properties of Ag@Au Nanoplates

Abstract A novel pressure-responsive polymer composite film was developed based on Ag@Au composite nanoplates (NPLs) and polyvinylpyrrolidone (PVP) by using Au nanoparticles as concentration reference. The orientation change of Ag@Au NPLs is impelled by the deformation of polymer matrix under pressu...

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Autores principales: Li-Shun Fu, Wen-Shou Wang, Cheng-Yan Xu, Yao Li, Liang Zhen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/0bbc0bc854914d3e924a702c552b0145
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Sumario:Abstract A novel pressure-responsive polymer composite film was developed based on Ag@Au composite nanoplates (NPLs) and polyvinylpyrrolidone (PVP) by using Au nanoparticles as concentration reference. The orientation change of Ag@Au NPLs is impelled by the deformation of polymer matrix under pressure, resulting in its localized surface plasmon resonance (LSPR) intensity change of in-plane dipolar peak. The intensity ratio between plasmon peak of Au nanoparticles and in-plane dipolar peak of Ag@Au NPLs relies on the intensity and duration of pressure. By adjusting the viscosity of the polymer, the orientation change of LSPR may respond to a wide range of stresses. This pressure sensitive film can be utilized to record the magnitude and distribution of pressure between two contacting surfaces via optical information.