Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach
Vibrational circular dichroism (VCD) spectroscopy can be useful for determining the absolute configuration of chiral molecules, as long as the signal intensities are high enough. Here, the authors establish the absolute configurations of two large chiral porphyrin cages and, notably, discover that h...
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2020
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oai:doaj.org-article:0c05c7c5df5042be898233ef4d5a7aa72021-12-02T18:14:23ZAbsolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach10.1038/s41467-020-18596-12041-1723https://doaj.org/article/0c05c7c5df5042be898233ef4d5a7aa72020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18596-1https://doaj.org/toc/2041-1723Vibrational circular dichroism (VCD) spectroscopy can be useful for determining the absolute configuration of chiral molecules, as long as the signal intensities are high enough. Here, the authors establish the absolute configurations of two large chiral porphyrin cages and, notably, discover that host-guest binding enhances their VCD intensities.Jiangkun OuyangAnne SwartjesMarc GeertsPieter J. GilissenDanni WangPaula C. P. TeeuwenPaul TinnemansNicolas VanthuyneSara ChentoufFloris P. J. T. RutjesJean-Valère NaubronJeanne CrassousJohannes A. A. W. ElemansRoeland J. M. NolteNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020) |
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| topic |
Science Q |
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Science Q Jiangkun Ouyang Anne Swartjes Marc Geerts Pieter J. Gilissen Danni Wang Paula C. P. Teeuwen Paul Tinnemans Nicolas Vanthuyne Sara Chentouf Floris P. J. T. Rutjes Jean-Valère Naubron Jeanne Crassous Johannes A. A. W. Elemans Roeland J. M. Nolte Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| description |
Vibrational circular dichroism (VCD) spectroscopy can be useful for determining the absolute configuration of chiral molecules, as long as the signal intensities are high enough. Here, the authors establish the absolute configurations of two large chiral porphyrin cages and, notably, discover that host-guest binding enhances their VCD intensities. |
| format |
article |
| author |
Jiangkun Ouyang Anne Swartjes Marc Geerts Pieter J. Gilissen Danni Wang Paula C. P. Teeuwen Paul Tinnemans Nicolas Vanthuyne Sara Chentouf Floris P. J. T. Rutjes Jean-Valère Naubron Jeanne Crassous Johannes A. A. W. Elemans Roeland J. M. Nolte |
| author_facet |
Jiangkun Ouyang Anne Swartjes Marc Geerts Pieter J. Gilissen Danni Wang Paula C. P. Teeuwen Paul Tinnemans Nicolas Vanthuyne Sara Chentouf Floris P. J. T. Rutjes Jean-Valère Naubron Jeanne Crassous Johannes A. A. W. Elemans Roeland J. M. Nolte |
| author_sort |
Jiangkun Ouyang |
| title |
Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| title_short |
Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| title_full |
Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| title_fullStr |
Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| title_full_unstemmed |
Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| title_sort |
absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach |
| publisher |
Nature Portfolio |
| publishDate |
2020 |
| url |
https://doaj.org/article/0c05c7c5df5042be898233ef4d5a7aa7 |
| work_keys_str_mv |
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1718378375356088320 |