Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives

In this study, oxalic acid was successfully loaded onto Fe3O4/PEG-400 under ultrasonic irradiation and Fe3O4/PEG/oxalic acid as a new nanomagnetic catalyst was synthesized. The chemical structure of the catalyst was investigated by the FT-IR, XRD, EDX and SEM methods. The catalyst was used for the s...

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Autores principales:	Esmaeilzadeh Seyran, Setamdideh Davood
Formato:	article
Lenguaje:	EN
Publicado:	Serbian Chemical Society 2021
Materias:	iron (ii) iron (iii) oxide nano-composite catalyst 2-pyrrolidinone green chemistry mcr Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/0ca81c07896f46faba7505ad79405789
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spelling	oai:doaj.org-article:0ca81c07896f46faba7505ad794057892021-11-22T11:03:40ZSynthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives0352-51391820-742110.2298/JSC210521059Ehttps://doaj.org/article/0ca81c07896f46faba7505ad794057892021-01-01T00:00:00Zhttp://www.doiserbia.nb.rs/img/doi/0352-5139/2021/0352-51392100059E.pdfhttps://doaj.org/toc/0352-5139https://doaj.org/toc/1820-7421In this study, oxalic acid was successfully loaded onto Fe3O4/PEG-400 under ultrasonic irradiation and Fe3O4/PEG/oxalic acid as a new nanomagnetic catalyst was synthesized. The chemical structure of the catalyst was investigated by the FT-IR, XRD, EDX and SEM methods. The catalyst was used for the synthesis of 3-acyl-5-hydroxy-3-pyrrolin-2-one derivatives from the corresponding aldehydes, anilines and dimethyl acetylenedicarboxylate (DMAD) by a one-pot and three-component MCR reaction in the excellent yields (90–95 %) of products within 24 h at room temperature. Fourteen samples are available. The recovered catalyst could be satisfactorily used for a second and third run without regeneration. This method has a green and eco-friendly profile. In addition, this research introduces an improved mechanism for these types of reaction. The chemical structures of new compounds was characterized by their FT-IR, 1H-NMR, 13C- -NMR and mass spectra.Esmaeilzadeh SeyranSetamdideh DavoodSerbian Chemical Society articleiron (ii) iron (iii) oxidenano-composite catalyst2-pyrrolidinonegreen chemistrymcrChemistryQD1-999ENJournal of the Serbian Chemical Society, Vol 86, Iss 11, Pp 1039-1052 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	iron (ii) iron (iii) oxide nano-composite catalyst 2-pyrrolidinone green chemistry mcr Chemistry QD1-999
spellingShingle	iron (ii) iron (iii) oxide nano-composite catalyst 2-pyrrolidinone green chemistry mcr Chemistry QD1-999 Esmaeilzadeh Seyran Setamdideh Davood Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
description	In this study, oxalic acid was successfully loaded onto Fe3O4/PEG-400 under ultrasonic irradiation and Fe3O4/PEG/oxalic acid as a new nanomagnetic catalyst was synthesized. The chemical structure of the catalyst was investigated by the FT-IR, XRD, EDX and SEM methods. The catalyst was used for the synthesis of 3-acyl-5-hydroxy-3-pyrrolin-2-one derivatives from the corresponding aldehydes, anilines and dimethyl acetylenedicarboxylate (DMAD) by a one-pot and three-component MCR reaction in the excellent yields (90–95 %) of products within 24 h at room temperature. Fourteen samples are available. The recovered catalyst could be satisfactorily used for a second and third run without regeneration. This method has a green and eco-friendly profile. In addition, this research introduces an improved mechanism for these types of reaction. The chemical structures of new compounds was characterized by their FT-IR, 1H-NMR, 13C- -NMR and mass spectra.
format	article
author	Esmaeilzadeh Seyran Setamdideh Davood
author_facet	Esmaeilzadeh Seyran Setamdideh Davood
author_sort	Esmaeilzadeh Seyran
title	Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
title_short	Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
title_full	Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
title_fullStr	Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
title_full_unstemmed	Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
title_sort	synthesis and characterization of fe3o4/peg-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives
publisher	Serbian Chemical Society
publishDate	2021
url	https://doaj.org/article/0ca81c07896f46faba7505ad79405789
work_keys_str_mv	AT esmaeilzadehseyran synthesisandcharacterizationoffe3o4peg400oxalicacidmagneticnanoparticlesasaheterogeneouscatalystforthesynthesisofpyrrolin2onesderivatives AT setamdidehdavood synthesisandcharacterizationoffe3o4peg400oxalicacidmagneticnanoparticlesasaheterogeneouscatalystforthesynthesisofpyrrolin2onesderivatives
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Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives

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