Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces

Abstract Superlattices of nanoparticles are generally produced based on solution chemistry processes. In this paper, we demonstrate that self-assembled monolayer structures of nanoparticles with superlattice periodicities can also be produced on template-free surfaces in the gas-phase cluster beam d...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Chang Liu, Fei Liu, Chen Jin, Sishi Zhang, Lianhua Zhang, Min Han
Formato:	article
Lenguaje:	EN
Publicado:	SpringerOpen 2021
Materias:	Ordered nanocluster monolayer Gas-phase cluster deposition Self-assembling Densely packed Surface migration Attractive interaction Materials of engineering and construction. Mechanics of materials TA401-492
Acceso en línea:	https://doaj.org/article/0cdd8eb198d54d8ba3a0f407a431b360
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:0cdd8eb198d54d8ba3a0f407a431b360
record_format	dspace
spelling	oai:doaj.org-article:0cdd8eb198d54d8ba3a0f407a431b3602021-12-05T12:23:55ZFormation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces10.1186/s11671-021-03635-71556-276Xhttps://doaj.org/article/0cdd8eb198d54d8ba3a0f407a431b3602021-11-01T00:00:00Zhttps://doi.org/10.1186/s11671-021-03635-7https://doaj.org/toc/1556-276XAbstract Superlattices of nanoparticles are generally produced based on solution chemistry processes. In this paper, we demonstrate that self-assembled monolayer structures of nanoparticles with superlattice periodicities can also be produced on template-free surfaces in the gas-phase cluster beam deposition process. It is found that the packing of Fe nanoparticles corresponds to an average of two-dimensional densely packed lattice with a hexagonal summary. By controlling the nanoparticle coverage, the two-dimensional densely packed monolayer morphology can spread to the whole substrate surface being deposited. A formation mechanism of the ordered monolayers is proposed. The densely packed morphologies are formed by the balance between the diffusion rate of the nanoparticles and their filling speed on the substrate surface determined by the deposition rate, and the ordering of the nanoparticle arrays is driven by the inter-particle attractive interactions. The model is strongly supported by a series of carefully designed cluster deposition experiments.Chang LiuFei LiuChen JinSishi ZhangLianhua ZhangMin HanSpringerOpenarticleOrdered nanocluster monolayerGas-phase cluster depositionSelf-assemblingDensely packedSurface migrationAttractive interactionMaterials of engineering and construction. Mechanics of materialsTA401-492ENNanoscale Research Letters, Vol 16, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Ordered nanocluster monolayer Gas-phase cluster deposition Self-assembling Densely packed Surface migration Attractive interaction Materials of engineering and construction. Mechanics of materials TA401-492
spellingShingle	Ordered nanocluster monolayer Gas-phase cluster deposition Self-assembling Densely packed Surface migration Attractive interaction Materials of engineering and construction. Mechanics of materials TA401-492 Chang Liu Fei Liu Chen Jin Sishi Zhang Lianhua Zhang Min Han Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces
description	Abstract Superlattices of nanoparticles are generally produced based on solution chemistry processes. In this paper, we demonstrate that self-assembled monolayer structures of nanoparticles with superlattice periodicities can also be produced on template-free surfaces in the gas-phase cluster beam deposition process. It is found that the packing of Fe nanoparticles corresponds to an average of two-dimensional densely packed lattice with a hexagonal summary. By controlling the nanoparticle coverage, the two-dimensional densely packed monolayer morphology can spread to the whole substrate surface being deposited. A formation mechanism of the ordered monolayers is proposed. The densely packed morphologies are formed by the balance between the diffusion rate of the nanoparticles and their filling speed on the substrate surface determined by the deposition rate, and the ordering of the nanoparticle arrays is driven by the inter-particle attractive interactions. The model is strongly supported by a series of carefully designed cluster deposition experiments.
format	article
author	Chang Liu Fei Liu Chen Jin Sishi Zhang Lianhua Zhang Min Han
author_facet	Chang Liu Fei Liu Chen Jin Sishi Zhang Lianhua Zhang Min Han
author_sort	Chang Liu
title	Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces
title_short	Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces
title_full	Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces
title_fullStr	Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces
title_full_unstemmed	Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces
title_sort	formation mechanism of well-ordered densely packed nanoparticle superlattices deposited from gas phase on template-free surfaces
publisher	SpringerOpen
publishDate	2021
url	https://doaj.org/article/0cdd8eb198d54d8ba3a0f407a431b360
work_keys_str_mv	AT changliu formationmechanismofwellordereddenselypackednanoparticlesuperlatticesdepositedfromgasphaseontemplatefreesurfaces AT feiliu formationmechanismofwellordereddenselypackednanoparticlesuperlatticesdepositedfromgasphaseontemplatefreesurfaces AT chenjin formationmechanismofwellordereddenselypackednanoparticlesuperlatticesdepositedfromgasphaseontemplatefreesurfaces AT sishizhang formationmechanismofwellordereddenselypackednanoparticlesuperlatticesdepositedfromgasphaseontemplatefreesurfaces AT lianhuazhang formationmechanismofwellordereddenselypackednanoparticlesuperlatticesdepositedfromgasphaseontemplatefreesurfaces AT minhan formationmechanismofwellordereddenselypackednanoparticlesuperlatticesdepositedfromgasphaseontemplatefreesurfaces
_version_	1718371940894244864

Formation Mechanism of Well-Ordered Densely Packed Nanoparticle Superlattices Deposited from Gas Phase on Template-Free Surfaces

Ejemplares similares