Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites
Many applications require hydrogen isotopes and so it is important to develop alternative separation technologies. Here, the authors report a metal-organic framework capable of capturing deuterium from H2/D2mixtures, and go on to predict selectivity for isotopologues containing tritium.
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Nature Portfolio
2017
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oai:doaj.org-article:0d0508254d94415da3c258821d25bda22021-12-02T15:38:36ZCapture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites10.1038/ncomms144962041-1723https://doaj.org/article/0d0508254d94415da3c258821d25bda22017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14496https://doaj.org/toc/2041-1723Many applications require hydrogen isotopes and so it is important to develop alternative separation technologies. Here, the authors report a metal-organic framework capable of capturing deuterium from H2/D2mixtures, and go on to predict selectivity for isotopologues containing tritium.I. WeinrauchI. SavchenkoD. DenysenkoS. M. SouliouH-H KimM. Le TaconL. L. DaemenY. ChengA. MavrandonakisA. J. Ramirez-CuestaD. VolkmerG. SchützM. HirscherT. HeineNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q |
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Science Q I. Weinrauch I. Savchenko D. Denysenko S. M. Souliou H-H Kim M. Le Tacon L. L. Daemen Y. Cheng A. Mavrandonakis A. J. Ramirez-Cuesta D. Volkmer G. Schütz M. Hirscher T. Heine Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites |
description |
Many applications require hydrogen isotopes and so it is important to develop alternative separation technologies. Here, the authors report a metal-organic framework capable of capturing deuterium from H2/D2mixtures, and go on to predict selectivity for isotopologues containing tritium. |
format |
article |
author |
I. Weinrauch I. Savchenko D. Denysenko S. M. Souliou H-H Kim M. Le Tacon L. L. Daemen Y. Cheng A. Mavrandonakis A. J. Ramirez-Cuesta D. Volkmer G. Schütz M. Hirscher T. Heine |
author_facet |
I. Weinrauch I. Savchenko D. Denysenko S. M. Souliou H-H Kim M. Le Tacon L. L. Daemen Y. Cheng A. Mavrandonakis A. J. Ramirez-Cuesta D. Volkmer G. Schütz M. Hirscher T. Heine |
author_sort |
I. Weinrauch |
title |
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites |
title_short |
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites |
title_full |
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites |
title_fullStr |
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites |
title_full_unstemmed |
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites |
title_sort |
capture of heavy hydrogen isotopes in a metal-organic framework with active cu(i) sites |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/0d0508254d94415da3c258821d25bda2 |
work_keys_str_mv |
AT iweinrauch captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT isavchenko captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT ddenysenko captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT smsouliou captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT hhkim captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT mletacon captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT lldaemen captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT ycheng captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT amavrandonakis captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT ajramirezcuesta captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT dvolkmer captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT gschutz captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT mhirscher captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites AT theine captureofheavyhydrogenisotopesinametalorganicframeworkwithactivecuisites |
_version_ |
1718386093309558784 |