Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions

The availability of low- cost adsorbent namely Al-Khriet ( a substance found in the legs of Typha Domingensis) as an agricultural waste material, for the removal of lead and cadmium from aqueous solution was investigated. In the batch tests experimental parameters were studied, including adsorbent...

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Autor principal:	Maha H. Al-Hassani
Formato:	article
Lenguaje:	EN
Publicado:	Al-Khwarizmi College of Engineering – University of Baghdad 2013
Materias:	Agricultural waste adsorbent Biosorption heavy metal ions isotherm kinetic model Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/0d33e0aa48d84497948cc3c57cc4e6bc
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spelling	oai:doaj.org-article:0d33e0aa48d84497948cc3c57cc4e6bc2021-12-02T10:53:11ZAl-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions1818-11712312-0789https://doaj.org/article/0d33e0aa48d84497948cc3c57cc4e6bc2013-06-01T00:00:00Zhttp://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/169https://doaj.org/toc/1818-1171https://doaj.org/toc/2312-0789 The availability of low- cost adsorbent namely Al-Khriet ( a substance found in the legs of Typha Domingensis) as an agricultural waste material, for the removal of lead and cadmium from aqueous solution was investigated. In the batch tests experimental parameters were studied, including adsorbent dosage between (0.2-1) g, initial metal ions concentration between (50-200) ppm (single and binary) and contact time (1/2-6) h. The removal percentage of each ion onto Al-Khriet reached equilibrium in about 4 hours. The highest adsorption capacity was for lead (96%) while for cadmium it was (90%) with 50 ppm ions concentration, 1 g dosage of adsorbent and pH 5.5. Adsorption capacity in the binary mixture were reduce at about 8% for lead and 12 % for cadmium, which was attributed to competitive adsorption. The adsorption parameters were analyzed using both the Freundlich and Langmuir. Al-Khriet was best fitted by the Freundlich isotherm comparing with Langmuir model, and the rate constant was found to be 1.305 and 0.621 ((mg/g)(L/mg)1/n) for lead and cadmium respectively , while the kinetic of adsorption obeyed a second order rate equation and the rate constants were found to be (0.0161) for lead and ( 0.0125) mg.g-1.min-1 for cadmium. Maha H. Al-HassaniAl-Khwarizmi College of Engineering – University of BaghdadarticleAgricultural waste adsorbentBiosorptionheavy metal ionsisotherm kinetic modelChemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 9, Iss 2 (2013)
institution	DOAJ
collection	DOAJ
language	EN
topic	Agricultural waste adsorbent Biosorption heavy metal ions isotherm kinetic model Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	Agricultural waste adsorbent Biosorption heavy metal ions isotherm kinetic model Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040 Maha H. Al-Hassani Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions
description	The availability of low- cost adsorbent namely Al-Khriet ( a substance found in the legs of Typha Domingensis) as an agricultural waste material, for the removal of lead and cadmium from aqueous solution was investigated. In the batch tests experimental parameters were studied, including adsorbent dosage between (0.2-1) g, initial metal ions concentration between (50-200) ppm (single and binary) and contact time (1/2-6) h. The removal percentage of each ion onto Al-Khriet reached equilibrium in about 4 hours. The highest adsorption capacity was for lead (96%) while for cadmium it was (90%) with 50 ppm ions concentration, 1 g dosage of adsorbent and pH 5.5. Adsorption capacity in the binary mixture were reduce at about 8% for lead and 12 % for cadmium, which was attributed to competitive adsorption. The adsorption parameters were analyzed using both the Freundlich and Langmuir. Al-Khriet was best fitted by the Freundlich isotherm comparing with Langmuir model, and the rate constant was found to be 1.305 and 0.621 ((mg/g)(L/mg)1/n) for lead and cadmium respectively , while the kinetic of adsorption obeyed a second order rate equation and the rate constants were found to be (0.0161) for lead and ( 0.0125) mg.g-1.min-1 for cadmium.
format	article
author	Maha H. Al-Hassani
author_facet	Maha H. Al-Hassani
author_sort	Maha H. Al-Hassani
title	Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions
title_short	Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions
title_full	Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions
title_fullStr	Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions
title_full_unstemmed	Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions
title_sort	al-khriet agricultural waste adsorbent, for removal lead and cadmium ion from aqueous solutions
publisher	Al-Khwarizmi College of Engineering – University of Baghdad
publishDate	2013
url	https://doaj.org/article/0d33e0aa48d84497948cc3c57cc4e6bc
work_keys_str_mv	AT mahahalhassani alkhrietagriculturalwasteadsorbentforremovalleadandcadmiumionfromaqueoussolutions
_version_	1718396511998443520

Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions

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