Ambiphilic boron in 1,4,2,5-diazadiborinine

Ambiphilic boron in 1,4,2,5-diazadiborinine

Boranes are archetypal Lewis acids owing to an empty p-orbital on the boron, although Lewis basic tricoordinate boranes have been developed too. Here, the authors report an annulated 1,4,2,5-diazadiborinine derivative with boron atoms that exhibit both Lewis acidic and basic properties.

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Autores principales: Baolin Wang, Yongxin Li, Rakesh Ganguly, Hajime Hirao, Rei Kinjo
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Q
Acceso en línea:https://doaj.org/article/0d36ae748ccc472d81ce997f98fe5673
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spelling oai:doaj.org-article:0d36ae748ccc472d81ce997f98fe56732021-12-02T14:38:56ZAmbiphilic boron in 1,4,2,5-diazadiborinine10.1038/ncomms118712041-1723https://doaj.org/article/0d36ae748ccc472d81ce997f98fe56732016-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms11871https://doaj.org/toc/2041-1723Boranes are archetypal Lewis acids owing to an empty p-orbital on the boron, although Lewis basic tricoordinate boranes have been developed too. Here, the authors report an annulated 1,4,2,5-diazadiborinine derivative with boron atoms that exhibit both Lewis acidic and basic properties.Baolin WangYongxin LiRakesh GangulyHajime HiraoRei KinjoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-10 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Baolin Wang
Yongxin Li
Rakesh Ganguly
Hajime Hirao
Rei Kinjo
Ambiphilic boron in 1,4,2,5-diazadiborinine
description Boranes are archetypal Lewis acids owing to an empty p-orbital on the boron, although Lewis basic tricoordinate boranes have been developed too. Here, the authors report an annulated 1,4,2,5-diazadiborinine derivative with boron atoms that exhibit both Lewis acidic and basic properties.
format article
author Baolin Wang
Yongxin Li
Rakesh Ganguly
Hajime Hirao
Rei Kinjo
author_facet Baolin Wang
Yongxin Li
Rakesh Ganguly
Hajime Hirao
Rei Kinjo
author_sort Baolin Wang
title Ambiphilic boron in 1,4,2,5-diazadiborinine
title_short Ambiphilic boron in 1,4,2,5-diazadiborinine
title_full Ambiphilic boron in 1,4,2,5-diazadiborinine
title_fullStr Ambiphilic boron in 1,4,2,5-diazadiborinine
title_full_unstemmed Ambiphilic boron in 1,4,2,5-diazadiborinine
title_sort ambiphilic boron in 1,4,2,5-diazadiborinine
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/0d36ae748ccc472d81ce997f98fe5673
work_keys_str_mv AT baolinwang ambiphilicboronin1425diazadiborinine
AT yongxinli ambiphilicboronin1425diazadiborinine
AT rakeshganguly ambiphilicboronin1425diazadiborinine
AT hajimehirao ambiphilicboronin1425diazadiborinine
AT reikinjo ambiphilicboronin1425diazadiborinine
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