Ambiphilic boron in 1,4,2,5-diazadiborinine

Boranes are archetypal Lewis acids owing to an empty p-orbital on the boron, although Lewis basic tricoordinate boranes have been developed too. Here, the authors report an annulated 1,4,2,5-diazadiborinine derivative with boron atoms that exhibit both Lewis acidic and basic properties.

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Detalles Bibliográficos
Autores principales: Baolin Wang, Yongxin Li, Rakesh Ganguly, Hajime Hirao, Rei Kinjo
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/0d36ae748ccc472d81ce997f98fe5673
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