Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles

Axially chiral arylpyrroles are structural motifs often found in natural and medicinal products. Here, the authors report the atroposelective synthesis of axially chiral arylpyrrole derivatives, which proved to be efficient chiral ligands for asymmetric catalysis, through desymmetrization and kineti...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Lei Zhang, Shao-Hua Xiang, Jun (Joelle) Wang, Jian Xiao, Jun-Qi Wang, Bin Tan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
Materias:
Q
Acceso en línea:https://doaj.org/article/0d9153db87224e71999d97ccc3260a2f
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:0d9153db87224e71999d97ccc3260a2f
record_format dspace
spelling oai:doaj.org-article:0d9153db87224e71999d97ccc3260a2f2021-12-02T17:31:53ZPhosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles10.1038/s41467-019-08447-z2041-1723https://doaj.org/article/0d9153db87224e71999d97ccc3260a2f2019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08447-zhttps://doaj.org/toc/2041-1723Axially chiral arylpyrroles are structural motifs often found in natural and medicinal products. Here, the authors report the atroposelective synthesis of axially chiral arylpyrrole derivatives, which proved to be efficient chiral ligands for asymmetric catalysis, through desymmetrization and kinetic resolution.Lei ZhangShao-Hua XiangJun (Joelle) WangJian XiaoJun-Qi WangBin TanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Lei Zhang
Shao-Hua Xiang
Jun (Joelle) Wang
Jian Xiao
Jun-Qi Wang
Bin Tan
Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
description Axially chiral arylpyrroles are structural motifs often found in natural and medicinal products. Here, the authors report the atroposelective synthesis of axially chiral arylpyrrole derivatives, which proved to be efficient chiral ligands for asymmetric catalysis, through desymmetrization and kinetic resolution.
format article
author Lei Zhang
Shao-Hua Xiang
Jun (Joelle) Wang
Jian Xiao
Jun-Qi Wang
Bin Tan
author_facet Lei Zhang
Shao-Hua Xiang
Jun (Joelle) Wang
Jian Xiao
Jun-Qi Wang
Bin Tan
author_sort Lei Zhang
title Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
title_short Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
title_full Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
title_fullStr Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
title_full_unstemmed Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
title_sort phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/0d9153db87224e71999d97ccc3260a2f
work_keys_str_mv AT leizhang phosphoricacidcatalyzedatroposelectiveconstructionofaxiallychiralarylpyrroles
AT shaohuaxiang phosphoricacidcatalyzedatroposelectiveconstructionofaxiallychiralarylpyrroles
AT junjoellewang phosphoricacidcatalyzedatroposelectiveconstructionofaxiallychiralarylpyrroles
AT jianxiao phosphoricacidcatalyzedatroposelectiveconstructionofaxiallychiralarylpyrroles
AT junqiwang phosphoricacidcatalyzedatroposelectiveconstructionofaxiallychiralarylpyrroles
AT bintan phosphoricacidcatalyzedatroposelectiveconstructionofaxiallychiralarylpyrroles
_version_ 1718380412185608192