Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents

A key difficulty to overcome in pyridinium salts functionalization is the regioselectivity at the two competing C2 and C4 sites. Here, the authors show bifunctional N-aminopyridinium salts reagents delivering both the aminyl radical and the pyridyl group to an olefin with C4-pyridyl regioselectivity...

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Autores principales:	Yonghoon Moon, Bohyun Park, Inwon Kim, Gyumin Kang, Sanghoon Shin, Dahye Kang, Mu-Hyun Baik, Sungwoo Hong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0dbe2b05121842239e7518e52f4af4ba
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spelling	oai:doaj.org-article:0dbe2b05121842239e7518e52f4af4ba2021-12-02T15:35:52ZVisible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents10.1038/s41467-019-12216-32041-1723https://doaj.org/article/0dbe2b05121842239e7518e52f4af4ba2019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12216-3https://doaj.org/toc/2041-1723A key difficulty to overcome in pyridinium salts functionalization is the regioselectivity at the two competing C2 and C4 sites. Here, the authors show bifunctional N-aminopyridinium salts reagents delivering both the aminyl radical and the pyridyl group to an olefin with C4-pyridyl regioselectivity.Yonghoon MoonBohyun ParkInwon KimGyumin KangSanghoon ShinDahye KangMu-Hyun BaikSungwoo HongNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yonghoon Moon Bohyun Park Inwon Kim Gyumin Kang Sanghoon Shin Dahye Kang Mu-Hyun Baik Sungwoo Hong Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
description	A key difficulty to overcome in pyridinium salts functionalization is the regioselectivity at the two competing C2 and C4 sites. Here, the authors show bifunctional N-aminopyridinium salts reagents delivering both the aminyl radical and the pyridyl group to an olefin with C4-pyridyl regioselectivity.
format	article
author	Yonghoon Moon Bohyun Park Inwon Kim Gyumin Kang Sanghoon Shin Dahye Kang Mu-Hyun Baik Sungwoo Hong
author_facet	Yonghoon Moon Bohyun Park Inwon Kim Gyumin Kang Sanghoon Shin Dahye Kang Mu-Hyun Baik Sungwoo Hong
author_sort	Yonghoon Moon
title	Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
title_short	Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
title_full	Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
title_fullStr	Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
title_full_unstemmed	Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
title_sort	visible light induced alkene aminopyridylation using n-aminopyridinium salts as bifunctional reagents
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/0dbe2b05121842239e7518e52f4af4ba
work_keys_str_mv	AT yonghoonmoon visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT bohyunpark visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT inwonkim visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT gyuminkang visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT sanghoonshin visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT dahyekang visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT muhyunbaik visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents AT sungwoohong visiblelightinducedalkeneaminopyridylationusingnaminopyridiniumsaltsasbifunctionalreagents
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Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents

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