Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane

Hydroxy-terminated oligomers with narrow molecular weight distribution using as soft segment of polyurethane can significantly increase the modulus, tensile strength, and elongation at break of the polyurethane. Thus, design and synthesis of new hydroxy-terminated oligomers having narrow molecular w...

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Autores principales:	Lingxiao Ma, Xiuzhong Zhu, Wanbin Zhang, Haitao Zhang, Jianyong Wang, Jianbo Qu
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Hydroxyl-terminated polybutadiene derivatives Post-polymerization modification Anionic polymerization Thiol-ene reaction Polyurethane elastomer Polymers and polymer manufacture TP1080-1185
Acceso en línea:	https://doaj.org/article/0df50c2b9a63421eb7ef8b878f2434f8
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spelling	oai:doaj.org-article:0df50c2b9a63421eb7ef8b878f2434f82021-11-14T04:27:57ZStudy on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane0142-941810.1016/j.polymertesting.2021.107389https://doaj.org/article/0df50c2b9a63421eb7ef8b878f2434f82021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S0142941821003342https://doaj.org/toc/0142-9418Hydroxy-terminated oligomers with narrow molecular weight distribution using as soft segment of polyurethane can significantly increase the modulus, tensile strength, and elongation at break of the polyurethane. Thus, design and synthesis of new hydroxy-terminated oligomers having narrow molecular weight distribution can improve the properties of polyurethane and further expand the use range of polyurethane. A set of side-chain hydroxyl-terminated polybutadiene (HTPB) derivatives were successfully synthesized by anionic polymerization and blue light photocatalytic thiol-ene reaction. Firstly, HTPB with narrow molecular weight distribution was synthesized via anionic polymerization using mono-lithium based initiator and followed by de-protection. Then, HTPB derivatives with different side-chains such as butyl, ethyl acetate, or myristyl, namely HTPBbut, HTPB eac and HTPBtet, were obtained by blue light photocatalytic thiol-ene reaction using Ru(bpy)3Cl2 as photoredox catalyst and HTPB as matrix polymer. Similar with HTPB, those HTPB derivatives also have narrow molecular weight distribution. Polyurethane elastomers (PUs) were synthesized with HTPB or HTPB derivatives as soft segment, toluene diisocynate (TDI) as hard segment, and 1, 4-butanediol as chain extender. Compared study the performances of polymers, the results showed that glass transition temperature (Tg) and viscosity of HTPB derivatives were increased when short-chain side groups were introduced. But instead, Tg and viscosity of HTPB derivatives was reduced following long-chain side groups being grafted. Through comparing research of properties for PUs, tensile strength is reduced and elongation at break is augmented, when side groups were introduced in HTPB backbone. Research on the contact angle tests of PUs indicated that the contact angle of PUs using HTPB, HTPBbut or HTPBeac as soft segment, is similar, and PUs using HTPBtet as soft segment has a larger contact angle about 137.2 °C.Lingxiao MaXiuzhong ZhuWanbin ZhangHaitao ZhangJianyong WangJianbo QuElsevierarticleHydroxyl-terminated polybutadiene derivativesPost-polymerization modificationAnionic polymerizationThiol-ene reactionPolyurethane elastomerPolymers and polymer manufactureTP1080-1185ENPolymer Testing, Vol 104, Iss , Pp 107389- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Hydroxyl-terminated polybutadiene derivatives Post-polymerization modification Anionic polymerization Thiol-ene reaction Polyurethane elastomer Polymers and polymer manufacture TP1080-1185
spellingShingle	Hydroxyl-terminated polybutadiene derivatives Post-polymerization modification Anionic polymerization Thiol-ene reaction Polyurethane elastomer Polymers and polymer manufacture TP1080-1185 Lingxiao Ma Xiuzhong Zhu Wanbin Zhang Haitao Zhang Jianyong Wang Jianbo Qu Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
description	Hydroxy-terminated oligomers with narrow molecular weight distribution using as soft segment of polyurethane can significantly increase the modulus, tensile strength, and elongation at break of the polyurethane. Thus, design and synthesis of new hydroxy-terminated oligomers having narrow molecular weight distribution can improve the properties of polyurethane and further expand the use range of polyurethane. A set of side-chain hydroxyl-terminated polybutadiene (HTPB) derivatives were successfully synthesized by anionic polymerization and blue light photocatalytic thiol-ene reaction. Firstly, HTPB with narrow molecular weight distribution was synthesized via anionic polymerization using mono-lithium based initiator and followed by de-protection. Then, HTPB derivatives with different side-chains such as butyl, ethyl acetate, or myristyl, namely HTPBbut, HTPB eac and HTPBtet, were obtained by blue light photocatalytic thiol-ene reaction using Ru(bpy)3Cl2 as photoredox catalyst and HTPB as matrix polymer. Similar with HTPB, those HTPB derivatives also have narrow molecular weight distribution. Polyurethane elastomers (PUs) were synthesized with HTPB or HTPB derivatives as soft segment, toluene diisocynate (TDI) as hard segment, and 1, 4-butanediol as chain extender. Compared study the performances of polymers, the results showed that glass transition temperature (Tg) and viscosity of HTPB derivatives were increased when short-chain side groups were introduced. But instead, Tg and viscosity of HTPB derivatives was reduced following long-chain side groups being grafted. Through comparing research of properties for PUs, tensile strength is reduced and elongation at break is augmented, when side groups were introduced in HTPB backbone. Research on the contact angle tests of PUs indicated that the contact angle of PUs using HTPB, HTPBbut or HTPBeac as soft segment, is similar, and PUs using HTPBtet as soft segment has a larger contact angle about 137.2 °C.
format	article
author	Lingxiao Ma Xiuzhong Zhu Wanbin Zhang Haitao Zhang Jianyong Wang Jianbo Qu
author_facet	Lingxiao Ma Xiuzhong Zhu Wanbin Zhang Haitao Zhang Jianyong Wang Jianbo Qu
author_sort	Lingxiao Ma
title	Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
title_short	Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
title_full	Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
title_fullStr	Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
title_full_unstemmed	Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
title_sort	study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/0df50c2b9a63421eb7ef8b878f2434f8
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Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane

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