Capture efficiency of four chamber designs for measuring ammonia emissions

Abstract Ammonia (NH3) emissions are an economically and environmentally significant loss pathway of fertilizer and soil‐derived N. Chambers are a commonly used method to quantify NH3 emissions in plot‐scale agricultural research. Although this method is widely used, its accuracy may be influenced b...

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Autores principales: Jonathan R. Alexander, Jared A. Spackman, Melissa L. Wilson, Fabián G. Fernández, Rodney T. Venterea
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Lenguaje:EN
Publicado: Wiley 2021
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Acceso en línea:https://doaj.org/article/0e65c73f52af458db41c8cbf43911023
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spelling oai:doaj.org-article:0e65c73f52af458db41c8cbf439110232021-11-24T11:36:04ZCapture efficiency of four chamber designs for measuring ammonia emissions2639-669610.1002/agg2.20199https://doaj.org/article/0e65c73f52af458db41c8cbf439110232021-01-01T00:00:00Zhttps://doi.org/10.1002/agg2.20199https://doaj.org/toc/2639-6696Abstract Ammonia (NH3) emissions are an economically and environmentally significant loss pathway of fertilizer and soil‐derived N. Chambers are a commonly used method to quantify NH3 emissions in plot‐scale agricultural research. Although this method is widely used, its accuracy may be influenced by the overall design of the chamber, its components, and its interaction with the environment. Four NH3 chamber designs, including open, open + polytetrafluoroethylene (PTFE), semi‐open, and closed, were deployed over a dilute NH3 solution for 6 h on four dates to determine the effect of chamber design on NH3 capture efficiency. The solution volume and concentration were measured before and after acid trap deployment, and total volatile NH3 emission was assumed to be equal to the mass N loss. The NH3 capture efficiency relative to the estimated total emissions was greatest for the open design (12.9%), whereas the semi‐open chamber was the least efficient (3.5%). The closed chamber reduced NH3 emissions relative to the open and semi‐open designs by inhibiting convective gas transport beneath the chamber footprint.Jonathan R. AlexanderJared A. SpackmanMelissa L. WilsonFabián G. FernándezRodney T. VentereaWileyarticleAgricultureSEnvironmental sciencesGE1-350ENAgrosystems, Geosciences & Environment, Vol 4, Iss 3, Pp n/a-n/a (2021)
institution DOAJ
collection DOAJ
language EN
topic Agriculture
S
Environmental sciences
GE1-350
spellingShingle Agriculture
S
Environmental sciences
GE1-350
Jonathan R. Alexander
Jared A. Spackman
Melissa L. Wilson
Fabián G. Fernández
Rodney T. Venterea
Capture efficiency of four chamber designs for measuring ammonia emissions
description Abstract Ammonia (NH3) emissions are an economically and environmentally significant loss pathway of fertilizer and soil‐derived N. Chambers are a commonly used method to quantify NH3 emissions in plot‐scale agricultural research. Although this method is widely used, its accuracy may be influenced by the overall design of the chamber, its components, and its interaction with the environment. Four NH3 chamber designs, including open, open + polytetrafluoroethylene (PTFE), semi‐open, and closed, were deployed over a dilute NH3 solution for 6 h on four dates to determine the effect of chamber design on NH3 capture efficiency. The solution volume and concentration were measured before and after acid trap deployment, and total volatile NH3 emission was assumed to be equal to the mass N loss. The NH3 capture efficiency relative to the estimated total emissions was greatest for the open design (12.9%), whereas the semi‐open chamber was the least efficient (3.5%). The closed chamber reduced NH3 emissions relative to the open and semi‐open designs by inhibiting convective gas transport beneath the chamber footprint.
format article
author Jonathan R. Alexander
Jared A. Spackman
Melissa L. Wilson
Fabián G. Fernández
Rodney T. Venterea
author_facet Jonathan R. Alexander
Jared A. Spackman
Melissa L. Wilson
Fabián G. Fernández
Rodney T. Venterea
author_sort Jonathan R. Alexander
title Capture efficiency of four chamber designs for measuring ammonia emissions
title_short Capture efficiency of four chamber designs for measuring ammonia emissions
title_full Capture efficiency of four chamber designs for measuring ammonia emissions
title_fullStr Capture efficiency of four chamber designs for measuring ammonia emissions
title_full_unstemmed Capture efficiency of four chamber designs for measuring ammonia emissions
title_sort capture efficiency of four chamber designs for measuring ammonia emissions
publisher Wiley
publishDate 2021
url https://doaj.org/article/0e65c73f52af458db41c8cbf43911023
work_keys_str_mv AT jonathanralexander captureefficiencyoffourchamberdesignsformeasuringammoniaemissions
AT jaredaspackman captureefficiencyoffourchamberdesignsformeasuringammoniaemissions
AT melissalwilson captureefficiencyoffourchamberdesignsformeasuringammoniaemissions
AT fabiangfernandez captureefficiencyoffourchamberdesignsformeasuringammoniaemissions
AT rodneytventerea captureefficiencyoffourchamberdesignsformeasuringammoniaemissions
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