Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis

Topochemical polymerization reactions produce ultra-high molecular weight crystalline polymers. Here the authors show a family of para-azaquinodimethane compounds that undergo facile visible light and thermally initiated polymerization in the solid state and the crystal structure has been resolved v...

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Autores principales: Christopher L. Anderson, He Li, Christopher G. Jones, Simon J. Teat, Nicholas S. Settineri, Eric A. Dailing, Jiatao Liang, Haiyan Mao, Chongqing Yang, Liana M. Klivansky, Xinle Li, Jeffrey A. Reimer, Hosea M. Nelson, Yi Liu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/0e6f6f51e3ce4ba59bfa86709d589551
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Sumario:Topochemical polymerization reactions produce ultra-high molecular weight crystalline polymers. Here the authors show a family of para-azaquinodimethane compounds that undergo facile visible light and thermally initiated polymerization in the solid state and the crystal structure has been resolved via cryoelectron microscopy.