Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes

Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides.

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Autores principales: Han Wang, Ren Wei Toh, Xiangcheng Shi, Tonglin Wang, Xu Cong, Jie Wu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/0ebe4211534f43f2911f4483ce256849
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spelling oai:doaj.org-article:0ebe4211534f43f2911f4483ce2568492021-12-02T19:13:48ZPhoto-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes10.1038/s41467-020-18274-22041-1723https://doaj.org/article/0ebe4211534f43f2911f4483ce2568492020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18274-2https://doaj.org/toc/2041-1723Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides.Han WangRen Wei TohXiangcheng ShiTonglin WangXu CongJie WuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Han Wang
Ren Wei Toh
Xiangcheng Shi
Tonglin Wang
Xu Cong
Jie Wu
Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
description Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides.
format article
author Han Wang
Ren Wei Toh
Xiangcheng Shi
Tonglin Wang
Xu Cong
Jie Wu
author_facet Han Wang
Ren Wei Toh
Xiangcheng Shi
Tonglin Wang
Xu Cong
Jie Wu
author_sort Han Wang
title Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
title_short Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
title_full Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
title_fullStr Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
title_full_unstemmed Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
title_sort photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/0ebe4211534f43f2911f4483ce256849
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AT renweitoh photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes
AT xiangchengshi photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes
AT tonglinwang photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes
AT xucong photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes
AT jiewu photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes
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