Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes
Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides.
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Nature Portfolio
2020
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oai:doaj.org-article:0ebe4211534f43f2911f4483ce2568492021-12-02T19:13:48ZPhoto-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes10.1038/s41467-020-18274-22041-1723https://doaj.org/article/0ebe4211534f43f2911f4483ce2568492020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18274-2https://doaj.org/toc/2041-1723Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides.Han WangRen Wei TohXiangcheng ShiTonglin WangXu CongJie WuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020) |
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Science Q Han Wang Ren Wei Toh Xiangcheng Shi Tonglin Wang Xu Cong Jie Wu Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
description |
Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides. |
format |
article |
author |
Han Wang Ren Wei Toh Xiangcheng Shi Tonglin Wang Xu Cong Jie Wu |
author_facet |
Han Wang Ren Wei Toh Xiangcheng Shi Tonglin Wang Xu Cong Jie Wu |
author_sort |
Han Wang |
title |
Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
title_short |
Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
title_full |
Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
title_fullStr |
Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
title_full_unstemmed |
Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
title_sort |
photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/0ebe4211534f43f2911f4483ce256849 |
work_keys_str_mv |
AT hanwang photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes AT renweitoh photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes AT xiangchengshi photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes AT tonglinwang photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes AT xucong photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes AT jiewu photomediatedselectivedeconstructivegeminaldihalogenationoftrisubstitutedalkenes |
_version_ |
1718377010608209920 |