Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design

The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Respo...

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Autores principales: Salfauqi Nurman, Saiful Saiful, Binawati Ginting, Rahmi Rahmi, Marlina Marlina
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Lenguaje:EN
Publicado: Department of Chemistry, Universitas Gadjah Mada 2021
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Acceso en línea:https://doaj.org/article/0ecc358467434e9b9cd238d110f3f811
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spelling oai:doaj.org-article:0ecc358467434e9b9cd238d110f3f8112021-12-02T18:41:51ZOptimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design1411-94202460-157810.22146/ijc.63649https://doaj.org/article/0ecc358467434e9b9cd238d110f3f8112021-05-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/63649https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Response Surface Methodology (RSM) using Software Design Expert Version 10.0.3.0 with three factors (TRL, TDI, and Glycerin). The F-value of 0.42 suggests that the membrane is less fit, while the P-value of 75.10% indicates that the quadratic design model is suitable for data analysis of physical characteristics. The optimal physical characteristics were obtained at a composition of 0.233 g TRL, 2.675 g TDI, and 0.254 g glycerin with a physical point of 6.5 (strong and elastic). Optimal polyurethane membrane has good thermal and mechanical properties at temperatures of Tg 58 °C, Tm 322 °C, and Td 534 °C, as well as stress and nominal strain values of 69.3 MPa and 5.74%. Polyurethane membrane synthesized from red seaweed has good physical properties. The result of this research is the basis for the development of polyurethane membrane applications from red seaweed.Salfauqi NurmanSaiful SaifulBinawati GintingRahmi RahmiMarlina MarlinaDepartment of Chemistry, Universitas Gadjah Madaarticlephysical characteristicsresponse surface methodologyoptimizationpolyurethane membranesChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 4, Pp 932-941 (2021)
institution DOAJ
collection DOAJ
language EN
topic physical characteristics
response surface methodology
optimization
polyurethane membranes
Chemistry
QD1-999
spellingShingle physical characteristics
response surface methodology
optimization
polyurethane membranes
Chemistry
QD1-999
Salfauqi Nurman
Saiful Saiful
Binawati Ginting
Rahmi Rahmi
Marlina Marlina
Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
description The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Response Surface Methodology (RSM) using Software Design Expert Version 10.0.3.0 with three factors (TRL, TDI, and Glycerin). The F-value of 0.42 suggests that the membrane is less fit, while the P-value of 75.10% indicates that the quadratic design model is suitable for data analysis of physical characteristics. The optimal physical characteristics were obtained at a composition of 0.233 g TRL, 2.675 g TDI, and 0.254 g glycerin with a physical point of 6.5 (strong and elastic). Optimal polyurethane membrane has good thermal and mechanical properties at temperatures of Tg 58 °C, Tm 322 °C, and Td 534 °C, as well as stress and nominal strain values of 69.3 MPa and 5.74%. Polyurethane membrane synthesized from red seaweed has good physical properties. The result of this research is the basis for the development of polyurethane membrane applications from red seaweed.
format article
author Salfauqi Nurman
Saiful Saiful
Binawati Ginting
Rahmi Rahmi
Marlina Marlina
author_facet Salfauqi Nurman
Saiful Saiful
Binawati Ginting
Rahmi Rahmi
Marlina Marlina
author_sort Salfauqi Nurman
title Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
title_short Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
title_full Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
title_fullStr Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
title_full_unstemmed Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
title_sort optimization of polyurethane membrane physical characteristics of red seaweed biomass using a box-behnken design
publisher Department of Chemistry, Universitas Gadjah Mada
publishDate 2021
url https://doaj.org/article/0ecc358467434e9b9cd238d110f3f811
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