Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design
The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Respo...
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Department of Chemistry, Universitas Gadjah Mada
2021
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oai:doaj.org-article:0ecc358467434e9b9cd238d110f3f8112021-12-02T18:41:51ZOptimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design1411-94202460-157810.22146/ijc.63649https://doaj.org/article/0ecc358467434e9b9cd238d110f3f8112021-05-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/63649https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Response Surface Methodology (RSM) using Software Design Expert Version 10.0.3.0 with three factors (TRL, TDI, and Glycerin). The F-value of 0.42 suggests that the membrane is less fit, while the P-value of 75.10% indicates that the quadratic design model is suitable for data analysis of physical characteristics. The optimal physical characteristics were obtained at a composition of 0.233 g TRL, 2.675 g TDI, and 0.254 g glycerin with a physical point of 6.5 (strong and elastic). Optimal polyurethane membrane has good thermal and mechanical properties at temperatures of Tg 58 °C, Tm 322 °C, and Td 534 °C, as well as stress and nominal strain values of 69.3 MPa and 5.74%. Polyurethane membrane synthesized from red seaweed has good physical properties. The result of this research is the basis for the development of polyurethane membrane applications from red seaweed.Salfauqi NurmanSaiful SaifulBinawati GintingRahmi RahmiMarlina MarlinaDepartment of Chemistry, Universitas Gadjah Madaarticlephysical characteristicsresponse surface methodologyoptimizationpolyurethane membranesChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 4, Pp 932-941 (2021) |
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physical characteristics response surface methodology optimization polyurethane membranes Chemistry QD1-999 |
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physical characteristics response surface methodology optimization polyurethane membranes Chemistry QD1-999 Salfauqi Nurman Saiful Saiful Binawati Ginting Rahmi Rahmi Marlina Marlina Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design |
description |
The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Response Surface Methodology (RSM) using Software Design Expert Version 10.0.3.0 with three factors (TRL, TDI, and Glycerin). The F-value of 0.42 suggests that the membrane is less fit, while the P-value of 75.10% indicates that the quadratic design model is suitable for data analysis of physical characteristics. The optimal physical characteristics were obtained at a composition of 0.233 g TRL, 2.675 g TDI, and 0.254 g glycerin with a physical point of 6.5 (strong and elastic). Optimal polyurethane membrane has good thermal and mechanical properties at temperatures of Tg 58 °C, Tm 322 °C, and Td 534 °C, as well as stress and nominal strain values of 69.3 MPa and 5.74%. Polyurethane membrane synthesized from red seaweed has good physical properties. The result of this research is the basis for the development of polyurethane membrane applications from red seaweed. |
format |
article |
author |
Salfauqi Nurman Saiful Saiful Binawati Ginting Rahmi Rahmi Marlina Marlina |
author_facet |
Salfauqi Nurman Saiful Saiful Binawati Ginting Rahmi Rahmi Marlina Marlina |
author_sort |
Salfauqi Nurman |
title |
Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design |
title_short |
Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design |
title_full |
Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design |
title_fullStr |
Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design |
title_full_unstemmed |
Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design |
title_sort |
optimization of polyurethane membrane physical characteristics of red seaweed biomass using a box-behnken design |
publisher |
Department of Chemistry, Universitas Gadjah Mada |
publishDate |
2021 |
url |
https://doaj.org/article/0ecc358467434e9b9cd238d110f3f811 |
work_keys_str_mv |
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