Organocatalyzed synthesis of fluorinated poly(aryl thioethers)

Fluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic...

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Autores principales:	Nathaniel H. Park, Gabriel dos Passos Gomes, Mareva Fevre, Gavin O. Jones, Igor V. Alabugin, James L. Hedrick
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0ecd61ec526244b7b2ab62ce50a86ce1
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spelling	oai:doaj.org-article:0ecd61ec526244b7b2ab62ce50a86ce12021-12-02T14:16:31ZOrganocatalyzed synthesis of fluorinated poly(aryl thioethers)10.1038/s41467-017-00186-32041-1723https://doaj.org/article/0ecd61ec526244b7b2ab62ce50a86ce12017-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00186-3https://doaj.org/toc/2041-1723Fluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic aromatic substitution of silyl-protected dithiols.Nathaniel H. ParkGabriel dos Passos GomesMareva FevreGavin O. JonesIgor V. AlabuginJames L. HedrickNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Nathaniel H. Park Gabriel dos Passos Gomes Mareva Fevre Gavin O. Jones Igor V. Alabugin James L. Hedrick Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
description	Fluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic aromatic substitution of silyl-protected dithiols.
format	article
author	Nathaniel H. Park Gabriel dos Passos Gomes Mareva Fevre Gavin O. Jones Igor V. Alabugin James L. Hedrick
author_facet	Nathaniel H. Park Gabriel dos Passos Gomes Mareva Fevre Gavin O. Jones Igor V. Alabugin James L. Hedrick
author_sort	Nathaniel H. Park
title	Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_short	Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_full	Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_fullStr	Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_full_unstemmed	Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_sort	organocatalyzed synthesis of fluorinated poly(aryl thioethers)
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/0ecd61ec526244b7b2ab62ce50a86ce1
work_keys_str_mv	AT nathanielhpark organocatalyzedsynthesisoffluorinatedpolyarylthioethers AT gabrieldospassosgomes organocatalyzedsynthesisoffluorinatedpolyarylthioethers AT marevafevre organocatalyzedsynthesisoffluorinatedpolyarylthioethers AT gavinojones organocatalyzedsynthesisoffluorinatedpolyarylthioethers AT igorvalabugin organocatalyzedsynthesisoffluorinatedpolyarylthioethers AT jameslhedrick organocatalyzedsynthesisoffluorinatedpolyarylthioethers
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Organocatalyzed synthesis of fluorinated poly(aryl thioethers)

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