Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations

Abstract Exploration of the mechanisms for growth of the nanostructures is the key point to achieve nanomaterial syntheses with precisely controlled morphology and structure. Herein, we reported a new mechanism that realized the growth of solid conical cap-closing hollow tube by axial screw dislocat...

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Autores principales: Yanhui Chu, Jinjin Li, Jikun Chen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/0ed9b800ec9d49d79733d96ebb60cec0
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spelling oai:doaj.org-article:0ed9b800ec9d49d79733d96ebb60cec02021-12-02T16:05:59ZSolid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations10.1038/s41598-017-03109-w2045-2322https://doaj.org/article/0ed9b800ec9d49d79733d96ebb60cec02017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-03109-whttps://doaj.org/toc/2045-2322Abstract Exploration of the mechanisms for growth of the nanostructures is the key point to achieve nanomaterial syntheses with precisely controlled morphology and structure. Herein, we reported a new mechanism that realized the growth of solid conical cap-closing hollow tube by axial screw dislocations in the formation α-Al2O3 nanowires. A hollow tube was firstly grown by axial screw dislocations in the formation α-Al2O3 nanowires through vapor-phase synthesis. Afterwards, the hollow tube was closed up by generating a solid conical cap with axial screw dislocations based on the competition between the surface energy and the strain energy of screw dislocation controlled by the growth environment. The solid conical cap-closing hollow tube growth model based on the axial screw dislocations is expected to be a general growth mechanism for nanowires within low supersaturation. This study enriches the fundamental understanding with respective to the kinetics of nanostructured crystal growth and provides guidance to the precise structure control in nanosynthesis and manufacturing.Yanhui ChuJinjin LiJikun ChenNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Yanhui Chu
Jinjin Li
Jikun Chen
Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations
description Abstract Exploration of the mechanisms for growth of the nanostructures is the key point to achieve nanomaterial syntheses with precisely controlled morphology and structure. Herein, we reported a new mechanism that realized the growth of solid conical cap-closing hollow tube by axial screw dislocations in the formation α-Al2O3 nanowires. A hollow tube was firstly grown by axial screw dislocations in the formation α-Al2O3 nanowires through vapor-phase synthesis. Afterwards, the hollow tube was closed up by generating a solid conical cap with axial screw dislocations based on the competition between the surface energy and the strain energy of screw dislocation controlled by the growth environment. The solid conical cap-closing hollow tube growth model based on the axial screw dislocations is expected to be a general growth mechanism for nanowires within low supersaturation. This study enriches the fundamental understanding with respective to the kinetics of nanostructured crystal growth and provides guidance to the precise structure control in nanosynthesis and manufacturing.
format article
author Yanhui Chu
Jinjin Li
Jikun Chen
author_facet Yanhui Chu
Jinjin Li
Jikun Chen
author_sort Yanhui Chu
title Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations
title_short Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations
title_full Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations
title_fullStr Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations
title_full_unstemmed Solid Conical Cap-closing Hollow Tube Growth by Axial Screw Dislocations
title_sort solid conical cap-closing hollow tube growth by axial screw dislocations
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/0ed9b800ec9d49d79733d96ebb60cec0
work_keys_str_mv AT yanhuichu solidconicalcapclosinghollowtubegrowthbyaxialscrewdislocations
AT jinjinli solidconicalcapclosinghollowtubegrowthbyaxialscrewdislocations
AT jikunchen solidconicalcapclosinghollowtubegrowthbyaxialscrewdislocations
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