Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−

Ternary heterometallic clusters often display intriguing structures and bonding. Here the authors prepare four [Sn2Sb5]3−-based clusters stabilized by coordination of a transition metal ion; analysis of their electronic structure reveals that the resulting cluster displays globally aromatic or antia...

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Autores principales:	Yu-He Xu, Nikolay V. Tkachenko, Ivan A. Popov, Lei Qiao, Alvaro Muñoz-Castro, Alexander I. Boldyrev, Zhong-Ming Sun
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0f1bd63d90984365852a3b07ae899293
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spelling	oai:doaj.org-article:0f1bd63d90984365852a3b07ae8992932021-12-02T17:57:16ZTernary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−10.1038/s41467-021-24706-42041-1723https://doaj.org/article/0f1bd63d90984365852a3b07ae8992932021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24706-4https://doaj.org/toc/2041-1723Ternary heterometallic clusters often display intriguing structures and bonding. Here the authors prepare four [Sn2Sb5]3−-based clusters stabilized by coordination of a transition metal ion; analysis of their electronic structure reveals that the resulting cluster displays globally aromatic or antiaromatic character depending on the transition metal ion.Yu-He XuNikolay V. TkachenkoIvan A. PopovLei QiaoAlvaro Muñoz-CastroAlexander I. BoldyrevZhong-Ming SunNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yu-He Xu Nikolay V. Tkachenko Ivan A. Popov Lei Qiao Alvaro Muñoz-Castro Alexander I. Boldyrev Zhong-Ming Sun Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−
description	Ternary heterometallic clusters often display intriguing structures and bonding. Here the authors prepare four [Sn2Sb5]3−-based clusters stabilized by coordination of a transition metal ion; analysis of their electronic structure reveals that the resulting cluster displays globally aromatic or antiaromatic character depending on the transition metal ion.
format	article
author	Yu-He Xu Nikolay V. Tkachenko Ivan A. Popov Lei Qiao Alvaro Muñoz-Castro Alexander I. Boldyrev Zhong-Ming Sun
author_facet	Yu-He Xu Nikolay V. Tkachenko Ivan A. Popov Lei Qiao Alvaro Muñoz-Castro Alexander I. Boldyrev Zhong-Ming Sun
author_sort	Yu-He Xu
title	Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−
title_short	Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−
title_full	Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−
title_fullStr	Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−
title_full_unstemmed	Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−
title_sort	ternary aromatic and anti-aromatic clusters derived from the hypho species [sn2sb5]3−
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/0f1bd63d90984365852a3b07ae899293
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Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−

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