Technology and some optical proprieties of nanocomposites PEPC/CuPc
A new structural nanocomposite (NC) based on oligomer poly(N-epoxypropyl)carbazole (PEPC) and copper phthalocyanine (CuPc) nanocrystals on a glass substrate are prepared by casting and droplet methods under normal conditions (room temperature, atmospheric pressure). Thin films of the PEPC/CuPc nanoc...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2013
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oai:doaj.org-article:0f3579f8806148bd9e64913acd1c38ce2021-11-21T11:59:50ZTechnology and some optical proprieties of nanocomposites PEPC/CuPc2537-63651810-648Xhttps://doaj.org/article/0f3579f8806148bd9e64913acd1c38ce2013-06-01T00:00:00Zhttps://mjps.nanotech.md/archive/2013/article/29781https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365A new structural nanocomposite (NC) based on oligomer poly(N-epoxypropyl)carbazole (PEPC) and copper phthalocyanine (CuPc) nanocrystals on a glass substrate are prepared by casting and droplet methods under normal conditions (room temperature, atmospheric pressure). Thin films of the PEPC/CuPc nanocomposite are characterized by visible optical, infrared (FT-IR), and photoluminescence (PL) spectra. The observed FT-IR bands are assigned to vibration modes of molecules and nanocrystals of CuPc on the basis of their symmetry. The optical spectra of PEPC/CuPc nanocomposites films show three main absorption bands attributed to CuPc, one band positioned at 1.46 eV, another one located at 2.02 eV, which is known as the π→ π* transitions in Q-bands and the π→ π* transitions of Soret B-band which was located at 3.02 eV. The effect of irradiation with ultraviolet (UV) light on the optical properties is studied.Bordian, OlgaCuleac, IonIovu, MihailVerlan, VictorPopuşoi, AnaPopuşoi, MihailRobu, ŞtefanDragalina, GalinaŞepeli, DianaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 12, Iss 3-4, Pp 229-237 (2013) |
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Physics QC1-999 Electronics TK7800-8360 |
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Physics QC1-999 Electronics TK7800-8360 Bordian, Olga Culeac, Ion Iovu, Mihail Verlan, Victor Popuşoi, Ana Popuşoi, Mihail Robu, Ştefan Dragalina, Galina Şepeli, Diana Technology and some optical proprieties of nanocomposites PEPC/CuPc |
description |
A new structural nanocomposite (NC) based on oligomer poly(N-epoxypropyl)carbazole (PEPC) and copper phthalocyanine (CuPc) nanocrystals on a glass substrate are prepared by casting and droplet methods under normal conditions (room temperature, atmospheric pressure). Thin films of the PEPC/CuPc nanocomposite are characterized by visible optical, infrared (FT-IR), and photoluminescence (PL) spectra. The observed FT-IR bands are assigned to vibration modes of molecules and nanocrystals of CuPc on the basis of their symmetry. The optical spectra of PEPC/CuPc nanocomposites films show three main absorption bands attributed to CuPc, one band positioned at 1.46 eV, another one located at 2.02 eV, which is known as the π→ π* transitions in Q-bands and the π→ π* transitions of Soret B-band which was located at 3.02 eV. The effect of irradiation with ultraviolet (UV) light on the optical properties is studied. |
format |
article |
author |
Bordian, Olga Culeac, Ion Iovu, Mihail Verlan, Victor Popuşoi, Ana Popuşoi, Mihail Robu, Ştefan Dragalina, Galina Şepeli, Diana |
author_facet |
Bordian, Olga Culeac, Ion Iovu, Mihail Verlan, Victor Popuşoi, Ana Popuşoi, Mihail Robu, Ştefan Dragalina, Galina Şepeli, Diana |
author_sort |
Bordian, Olga |
title |
Technology and some optical proprieties of nanocomposites PEPC/CuPc |
title_short |
Technology and some optical proprieties of nanocomposites PEPC/CuPc |
title_full |
Technology and some optical proprieties of nanocomposites PEPC/CuPc |
title_fullStr |
Technology and some optical proprieties of nanocomposites PEPC/CuPc |
title_full_unstemmed |
Technology and some optical proprieties of nanocomposites PEPC/CuPc |
title_sort |
technology and some optical proprieties of nanocomposites pepc/cupc |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2013 |
url |
https://doaj.org/article/0f3579f8806148bd9e64913acd1c38ce |
work_keys_str_mv |
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