Technology and some optical proprieties of nanocomposites PEPC/CuPc

A new structural nanocomposite (NC) based on oligomer poly(N-epoxypropyl)carbazole (PEPC) and copper phthalocyanine (CuPc) nanocrystals on a glass substrate are prepared by casting and droplet methods under normal conditions (room temperature, atmospheric pressure). Thin films of the PEPC/CuPc nanoc...

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Autores principales: Bordian, Olga, Culeac, Ion, Iovu, Mihail, Verlan, Victor, Popuşoi, Ana, Popuşoi, Mihail, Robu, Ştefan, Dragalina, Galina, Şepeli, Diana
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Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2013
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spelling oai:doaj.org-article:0f3579f8806148bd9e64913acd1c38ce2021-11-21T11:59:50ZTechnology and some optical proprieties of nanocomposites PEPC/CuPc2537-63651810-648Xhttps://doaj.org/article/0f3579f8806148bd9e64913acd1c38ce2013-06-01T00:00:00Zhttps://mjps.nanotech.md/archive/2013/article/29781https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365A new structural nanocomposite (NC) based on oligomer poly(N-epoxypropyl)carbazole (PEPC) and copper phthalocyanine (CuPc) nanocrystals on a glass substrate are prepared by casting and droplet methods under normal conditions (room temperature, atmospheric pressure). Thin films of the PEPC/CuPc nanocomposite are characterized by visible optical, infrared (FT-IR), and photoluminescence (PL) spectra. The observed FT-IR bands are assigned to vibration modes of molecules and nanocrystals of CuPc on the basis of their symmetry. The optical spectra of PEPC/CuPc nanocomposites films show three main absorption bands attributed to CuPc, one band positioned at 1.46 eV, another one located at 2.02 eV, which is known as the π→ π* transitions in Q-bands and the π→ π* transitions of Soret B-band which was located at 3.02 eV. The effect of irradiation with ultraviolet (UV) light on the optical properties is studied.Bordian, OlgaCuleac, IonIovu, MihailVerlan, VictorPopuşoi, AnaPopuşoi, MihailRobu, ŞtefanDragalina, GalinaŞepeli, DianaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 12, Iss 3-4, Pp 229-237 (2013)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Bordian, Olga
Culeac, Ion
Iovu, Mihail
Verlan, Victor
Popuşoi, Ana
Popuşoi, Mihail
Robu, Ştefan
Dragalina, Galina
Şepeli, Diana
Technology and some optical proprieties of nanocomposites PEPC/CuPc
description A new structural nanocomposite (NC) based on oligomer poly(N-epoxypropyl)carbazole (PEPC) and copper phthalocyanine (CuPc) nanocrystals on a glass substrate are prepared by casting and droplet methods under normal conditions (room temperature, atmospheric pressure). Thin films of the PEPC/CuPc nanocomposite are characterized by visible optical, infrared (FT-IR), and photoluminescence (PL) spectra. The observed FT-IR bands are assigned to vibration modes of molecules and nanocrystals of CuPc on the basis of their symmetry. The optical spectra of PEPC/CuPc nanocomposites films show three main absorption bands attributed to CuPc, one band positioned at 1.46 eV, another one located at 2.02 eV, which is known as the π→ π* transitions in Q-bands and the π→ π* transitions of Soret B-band which was located at 3.02 eV. The effect of irradiation with ultraviolet (UV) light on the optical properties is studied.
format article
author Bordian, Olga
Culeac, Ion
Iovu, Mihail
Verlan, Victor
Popuşoi, Ana
Popuşoi, Mihail
Robu, Ştefan
Dragalina, Galina
Şepeli, Diana
author_facet Bordian, Olga
Culeac, Ion
Iovu, Mihail
Verlan, Victor
Popuşoi, Ana
Popuşoi, Mihail
Robu, Ştefan
Dragalina, Galina
Şepeli, Diana
author_sort Bordian, Olga
title Technology and some optical proprieties of nanocomposites PEPC/CuPc
title_short Technology and some optical proprieties of nanocomposites PEPC/CuPc
title_full Technology and some optical proprieties of nanocomposites PEPC/CuPc
title_fullStr Technology and some optical proprieties of nanocomposites PEPC/CuPc
title_full_unstemmed Technology and some optical proprieties of nanocomposites PEPC/CuPc
title_sort technology and some optical proprieties of nanocomposites pepc/cupc
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2013
url https://doaj.org/article/0f3579f8806148bd9e64913acd1c38ce
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