A nine-atom rhodium–aluminum oxide cluster oxidizes five carbon monoxide molecules

Noble metals can promote the stable lattice oxygen of metal oxides to take part in oxidation reactions. Here, the authors report the preparation and reactivity of rhodium-aluminum oxide cluster ions, in which the rhodium ion promotes the transfer of five oxygen atoms from a nine-atom parent cluster...

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Autores principales: Xiao-Na Li, Hua-Min Zhang, Zhen Yuan, Sheng-Gui He
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/0f7058c07ec84653ae9ba4f143f1d168
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Sumario:Noble metals can promote the stable lattice oxygen of metal oxides to take part in oxidation reactions. Here, the authors report the preparation and reactivity of rhodium-aluminum oxide cluster ions, in which the rhodium ion promotes the transfer of five oxygen atoms from a nine-atom parent cluster to oxidize carbon monoxide.