NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY

Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in th...

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Autores principales:	DAME SEYE, CHEIKH ABDOUL KHADIR DIOP, ASSANE TOURE, LIBASSE DIOP
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2018
Materias:	bidentate bichelating discrete structure supramolecular architecture Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/0f747663504d4465814d2813890bf391
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spelling	oai:doaj.org-article:0f747663504d4465814d2813890bf3912021-12-02T19:52:43ZNEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY10.29081/jesr.v24i1.662068-75592344-4932https://doaj.org/article/0f747663504d4465814d2813890bf3912018-03-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/66https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained. DAME SEYE CHEIKH ABDOUL KHADIR DIOPASSANE TOURE LIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlebidentatebichelatingdiscrete structuresupramolecular architectureTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 24, Iss 1 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	bidentate bichelating discrete structure supramolecular architecture Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	bidentate bichelating discrete structure supramolecular architecture Technology T Engineering (General). Civil engineering (General) TA1-2040 DAME SEYE CHEIKH ABDOUL KHADIR DIOP ASSANE TOURE LIBASSE DIOP NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
description	Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained.
format	article
author	DAME SEYE CHEIKH ABDOUL KHADIR DIOP ASSANE TOURE LIBASSE DIOP
author_facet	DAME SEYE CHEIKH ABDOUL KHADIR DIOP ASSANE TOURE LIBASSE DIOP
author_sort	DAME SEYE
title	NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_short	NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_full	NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_fullStr	NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_full_unstemmed	NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_sort	new mx2 and m’cl3 (m = cu, zn; m’= y, dy, pr; x = cl, br) maleato complexes and tetraphenylantimony formiate adduct: synthesis and infrared study
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2018
url	https://doaj.org/article/0f747663504d4465814d2813890bf391
work_keys_str_mv	AT dameseye newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy AT cheikhabdoulkhadirdiop newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy AT assanetoure newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy AT libassediop newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy
_version_	1718375883613405184

NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY

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