Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone

Catalysts comprising copper and/or zinc supported on mesoporous silica-alumina (MSA) with a high Si/Al ratio were prepared by wet impregnation method. This study investigated the preparation, characterization, and catalytic application of the prepared catalysts for hydrotreatment cellulose-derived b...

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Autores principales:	Fahri Swasdika, Wega Trisunaryanti, Iip Izul Falah
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2020
Materias:	hydrotreatment bio-oil catalysis bifunctional catalyst mesoporous silica-alumina Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/10649fcb8f7a491d822401d13c42659c
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spelling	oai:doaj.org-article:10649fcb8f7a491d822401d13c42659c2021-12-02T12:51:19ZHydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone1411-94202460-157810.22146/ijc.50558https://doaj.org/article/10649fcb8f7a491d822401d13c42659c2020-10-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/50558https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578Catalysts comprising copper and/or zinc supported on mesoporous silica-alumina (MSA) with a high Si/Al ratio were prepared by wet impregnation method. This study investigated the preparation, characterization, and catalytic application of the prepared catalysts for hydrotreatment cellulose-derived bio-oil. The wet impregnation was performed by directly dispersing Cu(NO3)2·3H2O and/or Zn(NO3)2·4H2O aqueous solution into MSA, followed by calcination and reduction under H2 gas stream. The acidity test revealed that metal addition on MSA support increases the acidity of catalysts. During hydrotreatment of cellulose-derived bio-oil CuZn/MSA with total acidity, copper loading, zinc loading, and specific surface area of 24.86 mmol g–1, 5.23 wt.%, 3.15 wt.%, and 170.77 m2 g–1, respectively, exhibited the best performance compared to other prepared catalysts with 90.49 wt.% conversion of liquid product.Fahri SwasdikaWega TrisunaryantiIip Izul FalahDepartment of Chemistry, Universitas Gadjah Madaarticlehydrotreatmentbio-oilcatalysisbifunctional catalystmesoporous silica-aluminaChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 2, Pp 268-278 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	hydrotreatment bio-oil catalysis bifunctional catalyst mesoporous silica-alumina Chemistry QD1-999
spellingShingle	hydrotreatment bio-oil catalysis bifunctional catalyst mesoporous silica-alumina Chemistry QD1-999 Fahri Swasdika Wega Trisunaryanti Iip Izul Falah Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
description	Catalysts comprising copper and/or zinc supported on mesoporous silica-alumina (MSA) with a high Si/Al ratio were prepared by wet impregnation method. This study investigated the preparation, characterization, and catalytic application of the prepared catalysts for hydrotreatment cellulose-derived bio-oil. The wet impregnation was performed by directly dispersing Cu(NO3)2·3H2O and/or Zn(NO3)2·4H2O aqueous solution into MSA, followed by calcination and reduction under H2 gas stream. The acidity test revealed that metal addition on MSA support increases the acidity of catalysts. During hydrotreatment of cellulose-derived bio-oil CuZn/MSA with total acidity, copper loading, zinc loading, and specific surface area of 24.86 mmol g–1, 5.23 wt.%, 3.15 wt.%, and 170.77 m2 g–1, respectively, exhibited the best performance compared to other prepared catalysts with 90.49 wt.% conversion of liquid product.
format	article
author	Fahri Swasdika Wega Trisunaryanti Iip Izul Falah
author_facet	Fahri Swasdika Wega Trisunaryanti Iip Izul Falah
author_sort	Fahri Swasdika
title	Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
title_short	Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
title_full	Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
title_fullStr	Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
title_full_unstemmed	Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
title_sort	hydrotreatment of cellulose-derived bio-oil using copper and/or zinc catalysts supported on mesoporous silica-alumina synthesized from lapindo mud and catfish bone
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2020
url	https://doaj.org/article/10649fcb8f7a491d822401d13c42659c
work_keys_str_mv	AT fahriswasdika hydrotreatmentofcellulosederivedbiooilusingcopperandorzinccatalystssupportedonmesoporoussilicaaluminasynthesizedfromlapindomudandcatfishbone AT wegatrisunaryanti hydrotreatmentofcellulosederivedbiooilusingcopperandorzinccatalystssupportedonmesoporoussilicaaluminasynthesizedfromlapindomudandcatfishbone AT iipizulfalah hydrotreatmentofcellulosederivedbiooilusingcopperandorzinccatalystssupportedonmesoporoussilicaaluminasynthesizedfromlapindomudandcatfishbone
_version_	1718393608214675456

Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone

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