Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

Determining the covalency of actinide chemical bonding is a fundamentally important challenge. Here, the authors report a 15N nuclear magnetic resonance spectroscopy study of a terminal uranium-nitride, revealing exceptional NMR properties and covalency that redefine 15N NMR parameter space and acti...

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Autores principales:	Jingzhen Du, John A. Seed, Victoria E. J. Berryman, Nikolas Kaltsoyannis, Ralph W. Adams, Daniel Lee, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/109d4071717442b399b43eed3791e338
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spelling	oai:doaj.org-article:109d4071717442b399b43eed3791e3382021-12-02T18:14:31ZExceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis10.1038/s41467-021-25863-22041-1723https://doaj.org/article/109d4071717442b399b43eed3791e3382021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25863-2https://doaj.org/toc/2041-1723Determining the covalency of actinide chemical bonding is a fundamentally important challenge. Here, the authors report a 15N nuclear magnetic resonance spectroscopy study of a terminal uranium-nitride, revealing exceptional NMR properties and covalency that redefine 15N NMR parameter space and actinide chemical bonding.Jingzhen DuJohn A. SeedVictoria E. J. BerrymanNikolas KaltsoyannisRalph W. AdamsDaniel LeeStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jingzhen Du John A. Seed Victoria E. J. Berryman Nikolas Kaltsoyannis Ralph W. Adams Daniel Lee Stephen T. Liddle Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
description	Determining the covalency of actinide chemical bonding is a fundamentally important challenge. Here, the authors report a 15N nuclear magnetic resonance spectroscopy study of a terminal uranium-nitride, revealing exceptional NMR properties and covalency that redefine 15N NMR parameter space and actinide chemical bonding.
format	article
author	Jingzhen Du John A. Seed Victoria E. J. Berryman Nikolas Kaltsoyannis Ralph W. Adams Daniel Lee Stephen T. Liddle
author_facet	Jingzhen Du John A. Seed Victoria E. J. Berryman Nikolas Kaltsoyannis Ralph W. Adams Daniel Lee Stephen T. Liddle
author_sort	Jingzhen Du
title	Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
title_short	Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
title_full	Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
title_fullStr	Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
title_full_unstemmed	Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
title_sort	exceptional uranium(vi)-nitride triple bond covalency from 15n nuclear magnetic resonance spectroscopy and quantum chemical analysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/109d4071717442b399b43eed3791e338
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Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

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