Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase

Triclosan is a compound with antimicrobial activity broadly used in consumer products. Because of its well-documented toxicity, the amount of triclosan present in different products needs to be tightly controlled. This paper outlines a new amperometric sensor for triclosan detection consisting of...

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Autor principal: Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo
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Publicado: Pontificia Universidad Javeriana 2019
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Acceso en línea:https://doaj.org/article/10ced643cb074d758f142f36094c2d3c
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spelling oai:doaj.org-article:10ced643cb074d758f142f36094c2d3c2021-11-16T16:12:50ZAmperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase10.11144/Javeriana.SC24-2.adot0122-74832027-1352https://doaj.org/article/10ced643cb074d758f142f36094c2d3c2019-08-01T00:00:00Zhttps://revistas.javeriana.edu.co/index.php/scientarium/article/view/Javeriana.SC24-2.adothttps://doaj.org/toc/0122-7483https://doaj.org/toc/2027-1352Triclosan is a compound with antimicrobial activity broadly used in consumer products. Because of its well-documented toxicity, the amount of triclosan present in different products needs to be tightly controlled. This paper outlines a new amperometric sensor for triclosan detection consisting of a screen-printed carbon nanotube electrode (SPCNE) modified with Guinea grass peroxidase (GGP). The GGP-modified SPCNE was able to detect an enhanced electrochemical response of triclosan, unlike the bare SPCNE. The cyclic voltammograms of the GGP-modified SPCNE in a solution of potassium ferrocyanide showed an increase in the current values and linearity between scan rates and oxidation peak currents, suggesting a surface-controlled process. The GGP-modified SPCNE showed an excellent electrocatalytic activity to triclosan oxidation, at a redox potential of 370 mV, in the presence of hydrogen peroxide, exhibiting a linear response between 20 mM to 80 mM and a detection limit of 3 µM. This new amperometry system, based on carbon nanotubes integrated with GGP, becomes a potential tool for environmental analysis and food quality control.Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J CastilloPontificia Universidad Javerianaarticleamperometric biosensor; carbon nanotubes; guinea grass peroxidase; screen printed electrodes; triclosan.Science (General)Q1-390ENESUniversitas Scientiarum, Vol 24, Iss 2, Pp 363-379 (2019)
institution DOAJ
collection DOAJ
language EN
ES
topic amperometric biosensor; carbon nanotubes; guinea grass peroxidase; screen printed electrodes; triclosan.
Science (General)
Q1-390
spellingShingle amperometric biosensor; carbon nanotubes; guinea grass peroxidase; screen printed electrodes; triclosan.
Science (General)
Q1-390
Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo
Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
description Triclosan is a compound with antimicrobial activity broadly used in consumer products. Because of its well-documented toxicity, the amount of triclosan present in different products needs to be tightly controlled. This paper outlines a new amperometric sensor for triclosan detection consisting of a screen-printed carbon nanotube electrode (SPCNE) modified with Guinea grass peroxidase (GGP). The GGP-modified SPCNE was able to detect an enhanced electrochemical response of triclosan, unlike the bare SPCNE. The cyclic voltammograms of the GGP-modified SPCNE in a solution of potassium ferrocyanide showed an increase in the current values and linearity between scan rates and oxidation peak currents, suggesting a surface-controlled process. The GGP-modified SPCNE showed an excellent electrocatalytic activity to triclosan oxidation, at a redox potential of 370 mV, in the presence of hydrogen peroxide, exhibiting a linear response between 20 mM to 80 mM and a detection limit of 3 µM. This new amperometry system, based on carbon nanotubes integrated with GGP, becomes a potential tool for environmental analysis and food quality control.
format article
author Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo
author_facet Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo
author_sort Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo
title Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
title_short Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
title_full Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
title_fullStr Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
title_full_unstemmed Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
title_sort amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with guinea grass (panicum maximum) peroxidase
publisher Pontificia Universidad Javeriana
publishDate 2019
url https://doaj.org/article/10ced643cb074d758f142f36094c2d3c
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