Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase
Triclosan is a compound with antimicrobial activity broadly used in consumer products. Because of its well-documented toxicity, the amount of triclosan present in different products needs to be tightly controlled. This paper outlines a new amperometric sensor for triclosan detection consisting of...
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Pontificia Universidad Javeriana
2019
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oai:doaj.org-article:10ced643cb074d758f142f36094c2d3c2021-11-16T16:12:50ZAmperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase10.11144/Javeriana.SC24-2.adot0122-74832027-1352https://doaj.org/article/10ced643cb074d758f142f36094c2d3c2019-08-01T00:00:00Zhttps://revistas.javeriana.edu.co/index.php/scientarium/article/view/Javeriana.SC24-2.adothttps://doaj.org/toc/0122-7483https://doaj.org/toc/2027-1352Triclosan is a compound with antimicrobial activity broadly used in consumer products. Because of its well-documented toxicity, the amount of triclosan present in different products needs to be tightly controlled. This paper outlines a new amperometric sensor for triclosan detection consisting of a screen-printed carbon nanotube electrode (SPCNE) modified with Guinea grass peroxidase (GGP). The GGP-modified SPCNE was able to detect an enhanced electrochemical response of triclosan, unlike the bare SPCNE. The cyclic voltammograms of the GGP-modified SPCNE in a solution of potassium ferrocyanide showed an increase in the current values and linearity between scan rates and oxidation peak currents, suggesting a surface-controlled process. The GGP-modified SPCNE showed an excellent electrocatalytic activity to triclosan oxidation, at a redox potential of 370 mV, in the presence of hydrogen peroxide, exhibiting a linear response between 20 mM to 80 mM and a detection limit of 3 µM. This new amperometry system, based on carbon nanotubes integrated with GGP, becomes a potential tool for environmental analysis and food quality control.Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J CastilloPontificia Universidad Javerianaarticleamperometric biosensor; carbon nanotubes; guinea grass peroxidase; screen printed electrodes; triclosan.Science (General)Q1-390ENESUniversitas Scientiarum, Vol 24, Iss 2, Pp 363-379 (2019) |
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amperometric biosensor; carbon nanotubes; guinea grass peroxidase; screen printed electrodes; triclosan. Science (General) Q1-390 |
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amperometric biosensor; carbon nanotubes; guinea grass peroxidase; screen printed electrodes; triclosan. Science (General) Q1-390 Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase |
description |
Triclosan is a compound with antimicrobial activity broadly used in consumer
products. Because of its well-documented toxicity, the amount of triclosan
present in different products needs to be tightly controlled. This paper
outlines a new amperometric sensor for triclosan detection consisting of a
screen-printed carbon nanotube electrode (SPCNE) modified with Guinea
grass peroxidase (GGP). The GGP-modified SPCNE was able to detect an
enhanced electrochemical response of triclosan, unlike the bare SPCNE. The
cyclic voltammograms of the GGP-modified SPCNE in a solution of potassium
ferrocyanide showed an increase in the current values and linearity between
scan rates and oxidation peak currents, suggesting a surface-controlled process.
The GGP-modified SPCNE showed an excellent electrocatalytic activity to
triclosan oxidation, at a redox potential of 370 mV, in the presence of hydrogen
peroxide, exhibiting a linear response between 20 mM to 80 mM and a detection
limit of 3 µM. This new amperometry system, based on carbon nanotubes
integrated with GGP, becomes a potential tool for environmental analysis and
food quality control. |
format |
article |
author |
Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo |
author_facet |
Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo |
author_sort |
Angie E Orduz, Angie E Orduz, Sergio I Blanco, John J Castillo |
title |
Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase |
title_short |
Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase |
title_full |
Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase |
title_fullStr |
Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase |
title_full_unstemmed |
Amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with Guinea Grass (Panicum maximum) peroxidase |
title_sort |
amperometric detection of triclosan with screen-printed carbon nanotube electrodes modified with guinea grass (panicum maximum) peroxidase |
publisher |
Pontificia Universidad Javeriana |
publishDate |
2019 |
url |
https://doaj.org/article/10ced643cb074d758f142f36094c2d3c |
work_keys_str_mv |
AT angieeorduzangieeorduzsergioiblancojohnjcastillo amperometricdetectionoftriclosanwithscreenprintedcarbonnanotubeelectrodesmodifiedwithguineagrasspanicummaximumperoxidase |
_version_ |
1718426283395776512 |