Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV
Abstract In this work, the active carbon adsorption and TiO2/UV decolorization of black liquor were studied through experimental analysis (planned using Design of Experiments), modelling and optimization (with Response Surface Method and Differential Evolution). The aim is to highlight the importanc...
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oai:doaj.org-article:111879b3ffa344598f336a4bad300a942021-12-02T15:33:23ZDifferential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV10.1038/s41598-021-98006-82045-2322https://doaj.org/article/111879b3ffa344598f336a4bad300a942021-09-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-98006-8https://doaj.org/toc/2045-2322Abstract In this work, the active carbon adsorption and TiO2/UV decolorization of black liquor were studied through experimental analysis (planned using Design of Experiments), modelling and optimization (with Response Surface Method and Differential Evolution). The aim is to highlight the importance of optimization methods for increasing process efficiency. For active carbon adsorption, the considered process parameters were: quantity of active carbon, dilution, and contact time. For TiO2 promoted photochemical decolorization the process parameters were: TiO2 concentration, UV path length and irradiation time. The determined models had an R squared of 93.82% for active carbon adsorption and of 92.82% for TiO2/UV decolorization. The optimization of active carbon resulted in an improvement from 83.08% (corresponding to 50 g/L quantity of active carbon, 30 min contact time and 200 dilution) to 100% (corresponding to multiple combinations). The optimization of TiO2/UV decolorization indicated an increase of efficiency from 36.63% (corresponding to 1 g/L TiO2 concentration, 60 min irradiation time and 5 cm UV path length) to 46.83% (corresponding to 0.4 g/L TiO2 concentration, 59.99 min irradiation time and 2.85 cm UV path length). These results show that the experiments and the subsequent standard RSM optimization can be further improved, leading to better performance.Mircea Teodor NechitaGabriel Dan SudituAdrian Cătălin PuițelElena Niculina DrăgoiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-12 (2021) |
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Medicine R Science Q Mircea Teodor Nechita Gabriel Dan Suditu Adrian Cătălin Puițel Elena Niculina Drăgoi Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV |
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Abstract In this work, the active carbon adsorption and TiO2/UV decolorization of black liquor were studied through experimental analysis (planned using Design of Experiments), modelling and optimization (with Response Surface Method and Differential Evolution). The aim is to highlight the importance of optimization methods for increasing process efficiency. For active carbon adsorption, the considered process parameters were: quantity of active carbon, dilution, and contact time. For TiO2 promoted photochemical decolorization the process parameters were: TiO2 concentration, UV path length and irradiation time. The determined models had an R squared of 93.82% for active carbon adsorption and of 92.82% for TiO2/UV decolorization. The optimization of active carbon resulted in an improvement from 83.08% (corresponding to 50 g/L quantity of active carbon, 30 min contact time and 200 dilution) to 100% (corresponding to multiple combinations). The optimization of TiO2/UV decolorization indicated an increase of efficiency from 36.63% (corresponding to 1 g/L TiO2 concentration, 60 min irradiation time and 5 cm UV path length) to 46.83% (corresponding to 0.4 g/L TiO2 concentration, 59.99 min irradiation time and 2.85 cm UV path length). These results show that the experiments and the subsequent standard RSM optimization can be further improved, leading to better performance. |
format |
article |
author |
Mircea Teodor Nechita Gabriel Dan Suditu Adrian Cătălin Puițel Elena Niculina Drăgoi |
author_facet |
Mircea Teodor Nechita Gabriel Dan Suditu Adrian Cătălin Puițel Elena Niculina Drăgoi |
author_sort |
Mircea Teodor Nechita |
title |
Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV |
title_short |
Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV |
title_full |
Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV |
title_fullStr |
Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV |
title_full_unstemmed |
Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV |
title_sort |
differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and tio2/uv |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/111879b3ffa344598f336a4bad300a94 |
work_keys_str_mv |
AT mirceateodornechita differentialevolutionbasedoptimizationofcornstalksblackliquordecolorizationusingactivecarbonandtio2uv AT gabrieldansuditu differentialevolutionbasedoptimizationofcornstalksblackliquordecolorizationusingactivecarbonandtio2uv AT adriancatalinpuitel differentialevolutionbasedoptimizationofcornstalksblackliquordecolorizationusingactivecarbonandtio2uv AT elenaniculinadragoi differentialevolutionbasedoptimizationofcornstalksblackliquordecolorizationusingactivecarbonandtio2uv |
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