Is ortho-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel

The viability of the use of ortho-cresol as a bio-blendstock or antiknock additive from lignocellulosic biomass is assessed; Ignition delays of ortho-cresol within blends with iso-octane are measured with the ULille rapid compression machine,...

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Autores principales:	Carolina S. Mergulhão, Yann Fenard, Guillaume Vanhove
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	ignition delay low-temperature combustion ortho-cresol co-oxidation kinetic modeling rapid compression machine Technology T
Acceso en línea:	https://doaj.org/article/115eaa4b483f472f9b315463427dbad2
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id	oai:doaj.org-article:115eaa4b483f472f9b315463427dbad2
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spelling	oai:doaj.org-article:115eaa4b483f472f9b315463427dbad22021-11-11T15:55:17ZIs <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel10.3390/en142171051996-1073https://doaj.org/article/115eaa4b483f472f9b315463427dbad22021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/21/7105https://doaj.org/toc/1996-1073The viability of the use of <i>ortho</i>-cresol as a bio-blendstock or antiknock additive from lignocellulosic biomass is assessed; Ignition delays of <i>ortho</i>-cresol within blends with <i>iso</i>-octane are measured with the ULille rapid compression machine, and compared with results from the literature; It is shown that <i>ortho</i>-cresol has a strong inhibiting effect on the reactivity towards ignition, most notably in the Negative Temperature Coefficient region; This effect is found to originate from competition with <i>iso</i>-octane on the OH radicals, where the reactivity of <i>ortho</i>-cresol with these radicals does not lead to radical chain-branching.Carolina S. MergulhãoYann FenardGuillaume VanhoveMDPI AGarticleignition delaylow-temperature combustionortho-cresolco-oxidationkinetic modelingrapid compression machineTechnologyTENEnergies, Vol 14, Iss 7105, p 7105 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	ignition delay low-temperature combustion ortho-cresol co-oxidation kinetic modeling rapid compression machine Technology T
spellingShingle	ignition delay low-temperature combustion ortho-cresol co-oxidation kinetic modeling rapid compression machine Technology T Carolina S. Mergulhão Yann Fenard Guillaume Vanhove Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel
description	The viability of the use of <i>ortho</i>-cresol as a bio-blendstock or antiknock additive from lignocellulosic biomass is assessed; Ignition delays of <i>ortho</i>-cresol within blends with <i>iso</i>-octane are measured with the ULille rapid compression machine, and compared with results from the literature; It is shown that <i>ortho</i>-cresol has a strong inhibiting effect on the reactivity towards ignition, most notably in the Negative Temperature Coefficient region; This effect is found to originate from competition with <i>iso</i>-octane on the OH radicals, where the reactivity of <i>ortho</i>-cresol with these radicals does not lead to radical chain-branching.
format	article
author	Carolina S. Mergulhão Yann Fenard Guillaume Vanhove
author_facet	Carolina S. Mergulhão Yann Fenard Guillaume Vanhove
author_sort	Carolina S. Mergulhão
title	Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel
title_short	Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel
title_full	Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel
title_fullStr	Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel
title_full_unstemmed	Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel
title_sort	is <i>ortho</i>-cresol a viable lignocellulosic blendstock? a kinetic study of its co-oxidation within a surrogate fuel
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/115eaa4b483f472f9b315463427dbad2
work_keys_str_mv	AT carolinasmergulhao isiorthoicresolaviablelignocellulosicblendstockakineticstudyofitscooxidationwithinasurrogatefuel AT yannfenard isiorthoicresolaviablelignocellulosicblendstockakineticstudyofitscooxidationwithinasurrogatefuel AT guillaumevanhove isiorthoicresolaviablelignocellulosicblendstockakineticstudyofitscooxidationwithinasurrogatefuel
_version_	1718432837782208512

Is <i>ortho</i>-Cresol a Viable Lignocellulosic Blendstock? A Kinetic Study of Its Co-Oxidation within a Surrogate Fuel

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