Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath

The calculating of ionic equilibria in the system «Pb(CH3COO)2 - CdCl2 - Na3C6H5O7 - ‎(NH3)2(CH2)2 - N2H4CS» allowed us to find conditions and concentration regions of PbS and CdS co-deposition. The determined conditions provided the CBD obtaining of CdxPb1−xS (0 ≤ x ≤ 0.033) substitutional solid so...

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Autores principales:	A. D. Kutyavina, L. N. Maskaeva, V. I. Voronin, I. A. Anokhina, V. F. Markov
Formato:	article
Lenguaje:	EN RU
Publicado:	Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2021
Materias:	ethylenediamine-citrate bath boundary conditions chemical bath deposition thin films cdxpb1−xs solid solutions Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/12207b789a944575b2e09ebea1101739
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spelling	oai:doaj.org-article:12207b789a944575b2e09ebea11017392021-12-01T05:53:11ZMorphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath2411-141410.15826/chimtech.2021.8.2.10https://doaj.org/article/12207b789a944575b2e09ebea11017392021-06-01T00:00:00Zhttps://journals.urfu.ru/index.php/chimtech/article/view/5021https://doaj.org/toc/2411-1414The calculating of ionic equilibria in the system «Pb(CH3COO)2 - CdCl2 - Na3C6H5O7 - ‎(NH3)2(CH2)2 - N2H4CS» allowed us to find conditions and concentration regions of PbS and CdS co-deposition. The determined conditions provided the CBD obtaining of CdxPb1−xS (0 ≤ x ≤ 0.033) substitutional solid solutions films with a cubic structure B1 (space group Fm ) with the grains preferred orientation (200). We established the evolution of the surface morphology of the synthesized films from cubic crystallites to hierarchical structure of globular aggregates by scanning electron microscopy. A quantitative analysis of diffraction patterns showed a decrease of microstrains in CdxPb1−xS films by a about factor of 3 with an increase of the cadmium chloride concentration in the reaction mixture from 0.005 to 0.14 mol/l. The excess of the cadmium content, established by EDX analysis, in the studied films as compared to its content in the solid solution is associated with the additional formation of the amorphous CdS phase up to 72 mol %. A Corrigendum is available for this article at https://doi.org/10.15826/chimtech.2021.8.2.12.A. D. KutyavinaL. N. MaskaevaV. I. VoroninI. A. AnokhinaV. F. MarkovUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina articleethylenediamine-citrate bathboundary conditionschemical bath depositionthin filmscdxpb1−xs solid solutionsChemistryQD1-999ENRUChimica Techno Acta, Vol 8, Iss 2 (2021)
institution	DOAJ
collection	DOAJ
language	EN RU
topic	ethylenediamine-citrate bath boundary conditions chemical bath deposition thin films cdxpb1−xs solid solutions Chemistry QD1-999
spellingShingle	ethylenediamine-citrate bath boundary conditions chemical bath deposition thin films cdxpb1−xs solid solutions Chemistry QD1-999 A. D. Kutyavina L. N. Maskaeva V. I. Voronin I. A. Anokhina V. F. Markov Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath
description	The calculating of ionic equilibria in the system «Pb(CH3COO)2 - CdCl2 - Na3C6H5O7 - ‎(NH3)2(CH2)2 - N2H4CS» allowed us to find conditions and concentration regions of PbS and CdS co-deposition. The determined conditions provided the CBD obtaining of CdxPb1−xS (0 ≤ x ≤ 0.033) substitutional solid solutions films with a cubic structure B1 (space group Fm ) with the grains preferred orientation (200). We established the evolution of the surface morphology of the synthesized films from cubic crystallites to hierarchical structure of globular aggregates by scanning electron microscopy. A quantitative analysis of diffraction patterns showed a decrease of microstrains in CdxPb1−xS films by a about factor of 3 with an increase of the cadmium chloride concentration in the reaction mixture from 0.005 to 0.14 mol/l. The excess of the cadmium content, established by EDX analysis, in the studied films as compared to its content in the solid solution is associated with the additional formation of the amorphous CdS phase up to 72 mol %. A Corrigendum is available for this article at https://doi.org/10.15826/chimtech.2021.8.2.12.
format	article
author	A. D. Kutyavina L. N. Maskaeva V. I. Voronin I. A. Anokhina V. F. Markov
author_facet	A. D. Kutyavina L. N. Maskaeva V. I. Voronin I. A. Anokhina V. F. Markov
author_sort	A. D. Kutyavina
title	Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath
title_short	Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath
title_full	Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath
title_fullStr	Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath
title_full_unstemmed	Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath
title_sort	morphological and structural features of the cdxpb1−xs films obtained by cbd from ethylenediamine-citrate bath
publisher	Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
publishDate	2021
url	https://doaj.org/article/12207b789a944575b2e09ebea1101739
work_keys_str_mv	AT adkutyavina morphologicalandstructuralfeaturesofthecdxpb1xsfilmsobtainedbycbdfromethylenediaminecitratebath AT lnmaskaeva morphologicalandstructuralfeaturesofthecdxpb1xsfilmsobtainedbycbdfromethylenediaminecitratebath AT vivoronin morphologicalandstructuralfeaturesofthecdxpb1xsfilmsobtainedbycbdfromethylenediaminecitratebath AT iaanokhina morphologicalandstructuralfeaturesofthecdxpb1xsfilmsobtainedbycbdfromethylenediaminecitratebath AT vfmarkov morphologicalandstructuralfeaturesofthecdxpb1xsfilmsobtainedbycbdfromethylenediaminecitratebath
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Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath

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