Visible light-induced direct α C–H functionalization of alcohols

Alcohols are very useful building blocks in organic synthesis, however C–H functionaliztion in presence of free –OH groups is highly challenging. Here, the authors report a selective visible light-promoted α-functionalization of free alcohols with heteroarenes mediated by Selectofluor.

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Detalles Bibliográficos
Autores principales: Linbin Niu, Jiamei Liu, Xing-An Liang, Shengchun Wang, Aiwen Lei
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/12a8b47afd99453b9fd4578a86b1235e
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Sumario:Alcohols are very useful building blocks in organic synthesis, however C–H functionaliztion in presence of free –OH groups is highly challenging. Here, the authors report a selective visible light-promoted α-functionalization of free alcohols with heteroarenes mediated by Selectofluor.