Visible light-induced direct α C–H functionalization of alcohols
Alcohols are very useful building blocks in organic synthesis, however C–H functionaliztion in presence of free –OH groups is highly challenging. Here, the authors report a selective visible light-promoted α-functionalization of free alcohols with heteroarenes mediated by Selectofluor.
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Nature Portfolio
2019
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oai:doaj.org-article:12a8b47afd99453b9fd4578a86b1235e2021-12-02T15:35:48ZVisible light-induced direct α C–H functionalization of alcohols10.1038/s41467-019-08413-92041-1723https://doaj.org/article/12a8b47afd99453b9fd4578a86b1235e2019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08413-9https://doaj.org/toc/2041-1723Alcohols are very useful building blocks in organic synthesis, however C–H functionaliztion in presence of free –OH groups is highly challenging. Here, the authors report a selective visible light-promoted α-functionalization of free alcohols with heteroarenes mediated by Selectofluor.Linbin NiuJiamei LiuXing-An LiangShengchun WangAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019) |
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Science Q Linbin Niu Jiamei Liu Xing-An Liang Shengchun Wang Aiwen Lei Visible light-induced direct α C–H functionalization of alcohols |
description |
Alcohols are very useful building blocks in organic synthesis, however C–H functionaliztion in presence of free –OH groups is highly challenging. Here, the authors report a selective visible light-promoted α-functionalization of free alcohols with heteroarenes mediated by Selectofluor. |
format |
article |
author |
Linbin Niu Jiamei Liu Xing-An Liang Shengchun Wang Aiwen Lei |
author_facet |
Linbin Niu Jiamei Liu Xing-An Liang Shengchun Wang Aiwen Lei |
author_sort |
Linbin Niu |
title |
Visible light-induced direct α C–H functionalization of alcohols |
title_short |
Visible light-induced direct α C–H functionalization of alcohols |
title_full |
Visible light-induced direct α C–H functionalization of alcohols |
title_fullStr |
Visible light-induced direct α C–H functionalization of alcohols |
title_full_unstemmed |
Visible light-induced direct α C–H functionalization of alcohols |
title_sort |
visible light-induced direct α c–h functionalization of alcohols |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/12a8b47afd99453b9fd4578a86b1235e |
work_keys_str_mv |
AT linbinniu visiblelightinduceddirectachfunctionalizationofalcohols AT jiameiliu visiblelightinduceddirectachfunctionalizationofalcohols AT xinganliang visiblelightinduceddirectachfunctionalizationofalcohols AT shengchunwang visiblelightinduceddirectachfunctionalizationofalcohols AT aiwenlei visiblelightinduceddirectachfunctionalizationofalcohols |
_version_ |
1718386396135161856 |