Synthesis, structures and magnetic properties of [(η9-C9H9)Ln(η8-C8H8)] super sandwich complexes

Lanthanide sandwich complexes represent both a fundamental class of organometallic compounds and promising molecular magnets for information storage. Here the authors unveil a class of lanthanide sandwich complexes containing fully π-coordinated 8- and 9-membered rings, and show their slow relaxatio...

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Bibliographic Details
Main Authors: L. Münzfeld, C. Schoo, S. Bestgen, E. Moreno-Pineda, R. Köppe, M. Ruben, P. W. Roesky
Format: article
Language:EN
Published: Nature Portfolio 2019
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Online Access:https://doaj.org/article/12ee6e6b9b4d45f0afb01bf905bc39b6
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Summary:Lanthanide sandwich complexes represent both a fundamental class of organometallic compounds and promising molecular magnets for information storage. Here the authors unveil a class of lanthanide sandwich complexes containing fully π-coordinated 8- and 9-membered rings, and show their slow relaxation of the magnetization.