Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex
Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure
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Nature Portfolio
2019
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oai:doaj.org-article:139c48ef6def400aa029e0e9c54d0a922021-12-02T17:02:18ZTemperature dependence of spherical electron transfer in a nanosized [Fe14] complex10.1038/s41467-019-13279-y2041-1723https://doaj.org/article/139c48ef6def400aa029e0e9c54d0a922019-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13279-yhttps://doaj.org/toc/2041-1723Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structureWei HuangShuqi WuXiangwei GuYao LiAtsushi OkazawaNorimichi KojimaShinya HayamiMichael L. BakerPeter BencokMariko NoguchiYuji MiyazakiMotohiro NakanoTakumi NakanishiShinji KanegawaYuji InagakiTatsuya KawaeGui-Lin ZhuangYoshihito ShiotaKazunari YoshizawaDayu WuOsamu SatoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019) |
| institution |
DOAJ |
| collection |
DOAJ |
| language |
EN |
| topic |
Science Q |
| spellingShingle |
Science Q Wei Huang Shuqi Wu Xiangwei Gu Yao Li Atsushi Okazawa Norimichi Kojima Shinya Hayami Michael L. Baker Peter Bencok Mariko Noguchi Yuji Miyazaki Motohiro Nakano Takumi Nakanishi Shinji Kanegawa Yuji Inagaki Tatsuya Kawae Gui-Lin Zhuang Yoshihito Shiota Kazunari Yoshizawa Dayu Wu Osamu Sato Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| description |
Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure |
| format |
article |
| author |
Wei Huang Shuqi Wu Xiangwei Gu Yao Li Atsushi Okazawa Norimichi Kojima Shinya Hayami Michael L. Baker Peter Bencok Mariko Noguchi Yuji Miyazaki Motohiro Nakano Takumi Nakanishi Shinji Kanegawa Yuji Inagaki Tatsuya Kawae Gui-Lin Zhuang Yoshihito Shiota Kazunari Yoshizawa Dayu Wu Osamu Sato |
| author_facet |
Wei Huang Shuqi Wu Xiangwei Gu Yao Li Atsushi Okazawa Norimichi Kojima Shinya Hayami Michael L. Baker Peter Bencok Mariko Noguchi Yuji Miyazaki Motohiro Nakano Takumi Nakanishi Shinji Kanegawa Yuji Inagaki Tatsuya Kawae Gui-Lin Zhuang Yoshihito Shiota Kazunari Yoshizawa Dayu Wu Osamu Sato |
| author_sort |
Wei Huang |
| title |
Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_short |
Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_full |
Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_fullStr |
Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_full_unstemmed |
Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_sort |
temperature dependence of spherical electron transfer in a nanosized [fe14] complex |
| publisher |
Nature Portfolio |
| publishDate |
2019 |
| url |
https://doaj.org/article/139c48ef6def400aa029e0e9c54d0a92 |
| work_keys_str_mv |
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| _version_ |
1718381891702226944 |