Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect

Graphene p-n junctions have important applications in the fields of optical interconnection and low–power integrated circuits. Most current research is based on the lateral p-n junction prepared by chemical doping and other methods. Here, we report a new type of pure graphene oxide (pGO) vertical p-...

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Autores principales: Yan Fan, Tao Wang, Yinwei Qiu, Yinli Yang, Qiubo Pan, Jun Zheng, Songwei Zeng, Wei Liu, Gang Lou, Liang Chen
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/13f3166181364a9b9f01e0ac1c875650
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spelling oai:doaj.org-article:13f3166181364a9b9f01e0ac1c8756502021-11-25T18:27:47ZPure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect10.3390/molecules262268491420-3049https://doaj.org/article/13f3166181364a9b9f01e0ac1c8756502021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6849https://doaj.org/toc/1420-3049Graphene p-n junctions have important applications in the fields of optical interconnection and low–power integrated circuits. Most current research is based on the lateral p-n junction prepared by chemical doping and other methods. Here, we report a new type of pure graphene oxide (pGO) vertical p-n junctions which do not dope any other elements but only controls the oxygen content of GO. The I–V curve of the pGO vertical p–n junction demonstrates a remarkable rectification effect. In addition, the pGO vertical p–n junction shows stability of its rectification characteristic over long-term storage for six months when sealed and stored in a PE bag. Moreover, the pGO vertical p–n junctions have obvious photoelectric response and various rectification effects with different thicknesses and an oxygen content of GO, humidity, and temperature. Hall effect test results show that rGO is an n–type semiconductor; theoretical calculations and research show that GO is generally a p–type semiconductor with a bandgap, thereby forming a p–n junction. Our work provides a method for preparing undoped GO vertical p–n junctions with advantages such as simplicity, convenience, and large–scale industrial preparation. Our work demonstrates great potential for application in electronics and highly sensitive sensors.Yan FanTao WangYinwei QiuYinli YangQiubo PanJun ZhengSongwei ZengWei LiuGang LouLiang ChenMDPI AGarticleundoped p–n junctionvertical p–n junctiongraphene oxideOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6849, p 6849 (2021)
institution DOAJ
collection DOAJ
language EN
topic undoped p–n junction
vertical p–n junction
graphene oxide
Organic chemistry
QD241-441
spellingShingle undoped p–n junction
vertical p–n junction
graphene oxide
Organic chemistry
QD241-441
Yan Fan
Tao Wang
Yinwei Qiu
Yinli Yang
Qiubo Pan
Jun Zheng
Songwei Zeng
Wei Liu
Gang Lou
Liang Chen
Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect
description Graphene p-n junctions have important applications in the fields of optical interconnection and low–power integrated circuits. Most current research is based on the lateral p-n junction prepared by chemical doping and other methods. Here, we report a new type of pure graphene oxide (pGO) vertical p-n junctions which do not dope any other elements but only controls the oxygen content of GO. The I–V curve of the pGO vertical p–n junction demonstrates a remarkable rectification effect. In addition, the pGO vertical p–n junction shows stability of its rectification characteristic over long-term storage for six months when sealed and stored in a PE bag. Moreover, the pGO vertical p–n junctions have obvious photoelectric response and various rectification effects with different thicknesses and an oxygen content of GO, humidity, and temperature. Hall effect test results show that rGO is an n–type semiconductor; theoretical calculations and research show that GO is generally a p–type semiconductor with a bandgap, thereby forming a p–n junction. Our work provides a method for preparing undoped GO vertical p–n junctions with advantages such as simplicity, convenience, and large–scale industrial preparation. Our work demonstrates great potential for application in electronics and highly sensitive sensors.
format article
author Yan Fan
Tao Wang
Yinwei Qiu
Yinli Yang
Qiubo Pan
Jun Zheng
Songwei Zeng
Wei Liu
Gang Lou
Liang Chen
author_facet Yan Fan
Tao Wang
Yinwei Qiu
Yinli Yang
Qiubo Pan
Jun Zheng
Songwei Zeng
Wei Liu
Gang Lou
Liang Chen
author_sort Yan Fan
title Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect
title_short Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect
title_full Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect
title_fullStr Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect
title_full_unstemmed Pure Graphene Oxide Vertical p–n Junction with Remarkable Rectification Effect
title_sort pure graphene oxide vertical p–n junction with remarkable rectification effect
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/13f3166181364a9b9f01e0ac1c875650
work_keys_str_mv AT yanfan puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT taowang puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT yinweiqiu puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT yinliyang puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT qiubopan puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT junzheng puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT songweizeng puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT weiliu puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT ganglou puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
AT liangchen puregrapheneoxideverticalpnjunctionwithremarkablerectificationeffect
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