Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt
The structure of the title salt, ammonium carbamoylcyanonitrosomethanide, NH4+·C3H2N3O2−, features the co-existence of different hydrogen-bonding patterns, which are specific to each of the three functional groups (nitroso, carbamoyl and cyano) of the methanide anion. The nitroso O-atoms accept as m...
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International Union of Crystallography
2021
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oai:doaj.org-article:140ca9a30e37412c84616e04f5be0ff82021-11-12T11:16:09ZHydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt2056-989010.1107/S2056989021010239https://doaj.org/article/140ca9a30e37412c84616e04f5be0ff82021-11-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2056989021010239https://doaj.org/toc/2056-9890The structure of the title salt, ammonium carbamoylcyanonitrosomethanide, NH4+·C3H2N3O2−, features the co-existence of different hydrogen-bonding patterns, which are specific to each of the three functional groups (nitroso, carbamoyl and cyano) of the methanide anion. The nitroso O-atoms accept as many as three N—H...O bonds from the ammonium cations [N...O = 2.688 (3)–3.000 (3) Å] to form chains of fused rhombs [(NH4)(O)2]. The most prominent bonds of the carbamoyl groups are mutual and they yield 21 helices [N...O = 2.903 (2) Å], whereas the cyano N-atoms accept hydrogen bonds from sterically less accessible carbamoyl H-atoms [N...N = 3.004 (3) Å]. Two weaker NH4+...O=C bonds [N...O = 3.021 (2), 3.017 (2) Å] complete the hydrogen-bonded environment of the carbamoyl groups. A Hirshfeld surface analysis indicates that the most important interactions are overwhelmingly O...H/H...O and N...H/H...N, in total accounting for 64.1% of the contacts for the individual anions. The relatively simple scheme of these interactions allows the delineation of the supramolecular synthons, which may be applicable to crystal engineering of hydrogen-bonded solids containing polyfunctional methanide anions.Kostiantyn V. DomasevitchGanna A. SenchykAndrey B. LysenkoEduard B. RusanovInternational Union of Crystallographyarticlecrystal structurecarbamoylcyanonitrosomethanidesupramolecular synthonhydrogen bondingChemistryQD1-999ENActa Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 11, Pp 1103-1108 (2021) |
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crystal structure carbamoylcyanonitrosomethanide supramolecular synthon hydrogen bonding Chemistry QD1-999 |
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crystal structure carbamoylcyanonitrosomethanide supramolecular synthon hydrogen bonding Chemistry QD1-999 Kostiantyn V. Domasevitch Ganna A. Senchyk Andrey B. Lysenko Eduard B. Rusanov Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
description |
The structure of the title salt, ammonium carbamoylcyanonitrosomethanide, NH4+·C3H2N3O2−, features the co-existence of different hydrogen-bonding patterns, which are specific to each of the three functional groups (nitroso, carbamoyl and cyano) of the methanide anion. The nitroso O-atoms accept as many as three N—H...O bonds from the ammonium cations [N...O = 2.688 (3)–3.000 (3) Å] to form chains of fused rhombs [(NH4)(O)2]. The most prominent bonds of the carbamoyl groups are mutual and they yield 21 helices [N...O = 2.903 (2) Å], whereas the cyano N-atoms accept hydrogen bonds from sterically less accessible carbamoyl H-atoms [N...N = 3.004 (3) Å]. Two weaker NH4+...O=C bonds [N...O = 3.021 (2), 3.017 (2) Å] complete the hydrogen-bonded environment of the carbamoyl groups. A Hirshfeld surface analysis indicates that the most important interactions are overwhelmingly O...H/H...O and N...H/H...N, in total accounting for 64.1% of the contacts for the individual anions. The relatively simple scheme of these interactions allows the delineation of the supramolecular synthons, which may be applicable to crystal engineering of hydrogen-bonded solids containing polyfunctional methanide anions. |
format |
article |
author |
Kostiantyn V. Domasevitch Ganna A. Senchyk Andrey B. Lysenko Eduard B. Rusanov |
author_facet |
Kostiantyn V. Domasevitch Ganna A. Senchyk Andrey B. Lysenko Eduard B. Rusanov |
author_sort |
Kostiantyn V. Domasevitch |
title |
Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
title_short |
Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
title_full |
Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
title_fullStr |
Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
title_full_unstemmed |
Hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
title_sort |
hydrogen-bonding landscape of the carbamoylcyanonitrosomethanide anion in the crystal structure of its ammonium salt |
publisher |
International Union of Crystallography |
publishDate |
2021 |
url |
https://doaj.org/article/140ca9a30e37412c84616e04f5be0ff8 |
work_keys_str_mv |
AT kostiantynvdomasevitch hydrogenbondinglandscapeofthecarbamoylcyanonitrosomethanideanioninthecrystalstructureofitsammoniumsalt AT gannaasenchyk hydrogenbondinglandscapeofthecarbamoylcyanonitrosomethanideanioninthecrystalstructureofitsammoniumsalt AT andreyblysenko hydrogenbondinglandscapeofthecarbamoylcyanonitrosomethanideanioninthecrystalstructureofitsammoniumsalt AT eduardbrusanov hydrogenbondinglandscapeofthecarbamoylcyanonitrosomethanideanioninthecrystalstructureofitsammoniumsalt |
_version_ |
1718430602552672256 |