Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation

Developing robust catalysts for alkyne semi-hydrogenation remains a challenge. Here, the authors introduce a scalable protocol to prepare crystal phase and orientation controlled Pd3S nanoparticles supported on carbon nitride, exhibiting unparalleled semi-hydrogenation performance due to a high dens...

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Autores principales: Davide Albani, Masoud Shahrokhi, Zupeng Chen, Sharon Mitchell, Roland Hauert, Núria López, Javier Pérez-Ramírez
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/1412e0983c07435a8e26ec58780a3061
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Sumario:Developing robust catalysts for alkyne semi-hydrogenation remains a challenge. Here, the authors introduce a scalable protocol to prepare crystal phase and orientation controlled Pd3S nanoparticles supported on carbon nitride, exhibiting unparalleled semi-hydrogenation performance due to a high density of active and selective ensembles.