Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts

The processes of heterogeneous catalytic hydrogenation of carbonyl-containing compounds into the corresponding alcohols mostly occur under rather harsh conditions; therefore, catalysts and optimal parameters that facilitate the process under mild conditions need to be selected. New ways of synthesiz...

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Autores principales:	N.Kh. Khaldarov, S.Zh. Egemberdiyeva, Ye.I. Kistaubayev, Sh.K. Shapalov, R.F. Altynbekov
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Catalysis Hydrogenation Butyl aldehyde Butyl alcohol Skeletal nickel catalyst Rate Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/144a83040dc9409eac41a342aad7ecf1
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spelling	oai:doaj.org-article:144a83040dc9409eac41a342aad7ecf12021-11-16T04:09:16ZLiquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts1873-390510.1016/j.catcom.2021.106362https://doaj.org/article/144a83040dc9409eac41a342aad7ecf12021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1566736721000856https://doaj.org/toc/1873-3905The processes of heterogeneous catalytic hydrogenation of carbonyl-containing compounds into the corresponding alcohols mostly occur under rather harsh conditions; therefore, catalysts and optimal parameters that facilitate the process under mild conditions need to be selected. New ways of synthesizing catalytic systems and the use of harmless, environmentally friendly supercritical liquids as solvents are some of the key areas of green chemistry. At present, due to their high activity, two-component skeletal Ni catalysts are widely used in industry. This work attempts to develop highly efficient catalytic systems based on a three-component alloyed Ni catalyst containing metals (Ru, Rh) for the liquid-phase hydrogenation of aldehydes to butyl alcohols. The physicochemical and catalytic properties of modified alloyed Ni catalysts in the reaction of liquid-phase hydrogenation of butyl aldehyde to butyl alcohol have been investigated. Butyl aldehyde hydrogenation was carried out on a skeletal Ni catalyst promoted with ruthenium or rhodium in water at a temperature of 20–25 °C and the hydrogen pressure of 0.1 MPa. It was found that modified catalysts with high activity and selectivity reduce butyl aldehydes to butyl alcohols. The processes of catalyst preparation and butyl aldehyde hydrogenation are scalable and can be used in various processes of organic and petrochemical synthesis.N.Kh. KhaldarovS.Zh. EgemberdiyevaYe.I. KistaubayevSh.K. ShapalovR.F. AltynbekovElsevierarticleCatalysisHydrogenationButyl aldehydeButyl alcoholSkeletal nickel catalystRateChemistryQD1-999ENCatalysis Communications, Vol 161, Iss , Pp 106362- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Catalysis Hydrogenation Butyl aldehyde Butyl alcohol Skeletal nickel catalyst Rate Chemistry QD1-999
spellingShingle	Catalysis Hydrogenation Butyl aldehyde Butyl alcohol Skeletal nickel catalyst Rate Chemistry QD1-999 N.Kh. Khaldarov S.Zh. Egemberdiyeva Ye.I. Kistaubayev Sh.K. Shapalov R.F. Altynbekov Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
description	The processes of heterogeneous catalytic hydrogenation of carbonyl-containing compounds into the corresponding alcohols mostly occur under rather harsh conditions; therefore, catalysts and optimal parameters that facilitate the process under mild conditions need to be selected. New ways of synthesizing catalytic systems and the use of harmless, environmentally friendly supercritical liquids as solvents are some of the key areas of green chemistry. At present, due to their high activity, two-component skeletal Ni catalysts are widely used in industry. This work attempts to develop highly efficient catalytic systems based on a three-component alloyed Ni catalyst containing metals (Ru, Rh) for the liquid-phase hydrogenation of aldehydes to butyl alcohols. The physicochemical and catalytic properties of modified alloyed Ni catalysts in the reaction of liquid-phase hydrogenation of butyl aldehyde to butyl alcohol have been investigated. Butyl aldehyde hydrogenation was carried out on a skeletal Ni catalyst promoted with ruthenium or rhodium in water at a temperature of 20–25 °C and the hydrogen pressure of 0.1 MPa. It was found that modified catalysts with high activity and selectivity reduce butyl aldehydes to butyl alcohols. The processes of catalyst preparation and butyl aldehyde hydrogenation are scalable and can be used in various processes of organic and petrochemical synthesis.
format	article
author	N.Kh. Khaldarov S.Zh. Egemberdiyeva Ye.I. Kistaubayev Sh.K. Shapalov R.F. Altynbekov
author_facet	N.Kh. Khaldarov S.Zh. Egemberdiyeva Ye.I. Kistaubayev Sh.K. Shapalov R.F. Altynbekov
author_sort	N.Kh. Khaldarov
title	Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
title_short	Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
title_full	Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
title_fullStr	Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
title_full_unstemmed	Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
title_sort	liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/144a83040dc9409eac41a342aad7ecf1
work_keys_str_mv	AT nkhkhaldarov liquidphasehydrogenationofbutylaldehydepromotedonskeletalnickelcatalysts AT szhegemberdiyeva liquidphasehydrogenationofbutylaldehydepromotedonskeletalnickelcatalysts AT yeikistaubayev liquidphasehydrogenationofbutylaldehydepromotedonskeletalnickelcatalysts AT shkshapalov liquidphasehydrogenationofbutylaldehydepromotedonskeletalnickelcatalysts AT rfaltynbekov liquidphasehydrogenationofbutylaldehydepromotedonskeletalnickelcatalysts
_version_	1718426768525754368

Liquid-phase hydrogenation of butyl aldehyde promoted on skeletal nickel catalysts

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