Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review

Medium and highly sulfidic tailings are high-volume wastes that can lead to severe environmental damage if not properly managed. Due to the high content of sulfide minerals, these tailings can undergo weathering if put in contact with oxygen and water, generating acid mine drainage (AMD). The modera...

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Autores principales: Natalia Pires Martins, Sumit Srivastava, Francisco Veiga Simão, He Niu, Priyadharshini Perumal, Ruben Snellings, Mirja Illikainen, Hilde Chambart, Guillaume Habert
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/1500ee707e294e7da76392e7aea816ff
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spelling oai:doaj.org-article:1500ee707e294e7da76392e7aea816ff2021-11-11T19:46:09ZExploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review10.3390/su1321121502071-1050https://doaj.org/article/1500ee707e294e7da76392e7aea816ff2021-11-01T00:00:00Zhttps://www.mdpi.com/2071-1050/13/21/12150https://doaj.org/toc/2071-1050Medium and highly sulfidic tailings are high-volume wastes that can lead to severe environmental damage if not properly managed. Due to the high content of sulfide minerals, these tailings can undergo weathering if put in contact with oxygen and water, generating acid mine drainage (AMD). The moderate-to-high sulfide content is also an important technical limitation for their implementation in the production of construction materials. This paper reviews the use of sulfidic tailings as raw material in construction products, with a focus on cement, concrete, and ceramics. When used as aggregates in concrete, this can lead to concrete degradation by internal sulfate attack. In building ceramics, their implementation without prior treatment is undesirable due to the formation of black reduction core, efflorescence, SO<sub>x</sub> emissions, and their associated costs. Moreover, their intrinsic low reactivity represents a barrier for their use as supplementary cementitious materials (SCMs) and as precursors for alkali-activated materials (AAMs). Nevertheless, the production of calcium sulfoaluminate (CSA) cement can be a suitable path for the valorization of medium and highly sulfidic tailings. Otherwise difficult to upcycle, sulfidic tailings could be used in the clinker raw meal as an alternative raw material. Not only the SO<sub>3</sub> and SiO<sub>2</sub>-rich bulk material is incorporated into reactive clinker phases, but also some minor constituents in the tailings may contribute to the production of such low-CO<sub>2</sub> cements at lower temperatures. Nevertheless, this valorization route remains poorly explored and demands further research.Natalia Pires MartinsSumit SrivastavaFrancisco Veiga SimãoHe NiuPriyadharshini PerumalRuben SnellingsMirja IllikainenHilde ChambartGuillaume HabertMDPI AGarticlevalorizationcalcium sulfoaluminate cementceramicsalkali-activated materialsaggregatesEnvironmental effects of industries and plantsTD194-195Renewable energy sourcesTJ807-830Environmental sciencesGE1-350ENSustainability, Vol 13, Iss 12150, p 12150 (2021)
institution DOAJ
collection DOAJ
language EN
topic valorization
calcium sulfoaluminate cement
ceramics
alkali-activated materials
aggregates
Environmental effects of industries and plants
TD194-195
Renewable energy sources
TJ807-830
Environmental sciences
GE1-350
spellingShingle valorization
calcium sulfoaluminate cement
ceramics
alkali-activated materials
aggregates
Environmental effects of industries and plants
TD194-195
Renewable energy sources
TJ807-830
Environmental sciences
GE1-350
Natalia Pires Martins
Sumit Srivastava
Francisco Veiga Simão
He Niu
Priyadharshini Perumal
Ruben Snellings
Mirja Illikainen
Hilde Chambart
Guillaume Habert
Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review
description Medium and highly sulfidic tailings are high-volume wastes that can lead to severe environmental damage if not properly managed. Due to the high content of sulfide minerals, these tailings can undergo weathering if put in contact with oxygen and water, generating acid mine drainage (AMD). The moderate-to-high sulfide content is also an important technical limitation for their implementation in the production of construction materials. This paper reviews the use of sulfidic tailings as raw material in construction products, with a focus on cement, concrete, and ceramics. When used as aggregates in concrete, this can lead to concrete degradation by internal sulfate attack. In building ceramics, their implementation without prior treatment is undesirable due to the formation of black reduction core, efflorescence, SO<sub>x</sub> emissions, and their associated costs. Moreover, their intrinsic low reactivity represents a barrier for their use as supplementary cementitious materials (SCMs) and as precursors for alkali-activated materials (AAMs). Nevertheless, the production of calcium sulfoaluminate (CSA) cement can be a suitable path for the valorization of medium and highly sulfidic tailings. Otherwise difficult to upcycle, sulfidic tailings could be used in the clinker raw meal as an alternative raw material. Not only the SO<sub>3</sub> and SiO<sub>2</sub>-rich bulk material is incorporated into reactive clinker phases, but also some minor constituents in the tailings may contribute to the production of such low-CO<sub>2</sub> cements at lower temperatures. Nevertheless, this valorization route remains poorly explored and demands further research.
format article
author Natalia Pires Martins
Sumit Srivastava
Francisco Veiga Simão
He Niu
Priyadharshini Perumal
Ruben Snellings
Mirja Illikainen
Hilde Chambart
Guillaume Habert
author_facet Natalia Pires Martins
Sumit Srivastava
Francisco Veiga Simão
He Niu
Priyadharshini Perumal
Ruben Snellings
Mirja Illikainen
Hilde Chambart
Guillaume Habert
author_sort Natalia Pires Martins
title Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review
title_short Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review
title_full Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review
title_fullStr Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review
title_full_unstemmed Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review
title_sort exploring the potential for utilization of medium and highly sulfidic mine tailings in construction materials: a review
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/1500ee707e294e7da76392e7aea816ff
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