Fe-N system at high pressure reveals a compound featuring polymeric nitrogen chains

Owing to the energetic nature of N–N bonds, poly-nitrogen compounds are considered promising high energy density materials. Here, the authors synthesize three iron–nitrogen compounds at high pressure, including FeN4, which features polymeric nitrogen chains of [N4 2−] n units.

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Detalles Bibliográficos
Autores principales: M. Bykov, E. Bykova, G. Aprilis, K. Glazyrin, E. Koemets, I. Chuvashova, I. Kupenko, C. McCammon, M. Mezouar, V. Prakapenka, H.-P. Liermann, F. Tasnádi, A. V. Ponomareva, I. A. Abrikosov, N. Dubrovinskaia, L. Dubrovinsky
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/15491df9fe9f44a09cb6e13a4655b340
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Sumario:Owing to the energetic nature of N–N bonds, poly-nitrogen compounds are considered promising high energy density materials. Here, the authors synthesize three iron–nitrogen compounds at high pressure, including FeN4, which features polymeric nitrogen chains of [N4 2−] n units.