Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes

α-Pyridones and α-pyrones are ubiquitous structural motifs found in natural products and components of biologically active small molecules. Here, the authors report an oxidant-free Rh-catalyzed electrochemical divergent vinylic C–H annulation of acrylamides with alkynes to α-pyridones and cyclic imi...

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Autores principales:	Yi-Kang Xing, Xin-Ran Chen, Qi-Liang Yang, Shuo-Qing Zhang, Hai-Ming Guo, Xin Hong, Tian-Sheng Mei
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/15529b8012124328b09b94ad4ae6e9ac
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spelling	oai:doaj.org-article:15529b8012124328b09b94ad4ae6e9ac2021-12-02T12:09:04ZDivergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes10.1038/s41467-021-21190-82041-1723https://doaj.org/article/15529b8012124328b09b94ad4ae6e9ac2021-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21190-8https://doaj.org/toc/2041-1723α-Pyridones and α-pyrones are ubiquitous structural motifs found in natural products and components of biologically active small molecules. Here, the authors report an oxidant-free Rh-catalyzed electrochemical divergent vinylic C–H annulation of acrylamides with alkynes to α-pyridones and cyclic imidates.Yi-Kang XingXin-Ran ChenQi-Liang YangShuo-Qing ZhangHai-Ming GuoXin HongTian-Sheng MeiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yi-Kang Xing Xin-Ran Chen Qi-Liang Yang Shuo-Qing Zhang Hai-Ming Guo Xin Hong Tian-Sheng Mei Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
description	α-Pyridones and α-pyrones are ubiquitous structural motifs found in natural products and components of biologically active small molecules. Here, the authors report an oxidant-free Rh-catalyzed electrochemical divergent vinylic C–H annulation of acrylamides with alkynes to α-pyridones and cyclic imidates.
format	article
author	Yi-Kang Xing Xin-Ran Chen Qi-Liang Yang Shuo-Qing Zhang Hai-Ming Guo Xin Hong Tian-Sheng Mei
author_facet	Yi-Kang Xing Xin-Ran Chen Qi-Liang Yang Shuo-Qing Zhang Hai-Ming Guo Xin Hong Tian-Sheng Mei
author_sort	Yi-Kang Xing
title	Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
title_short	Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
title_full	Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
title_fullStr	Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
title_full_unstemmed	Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes
title_sort	divergent rhodium-catalyzed electrochemical vinylic c–h annulation of acrylamides with alkynes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/15529b8012124328b09b94ad4ae6e9ac
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Divergent rhodium-catalyzed electrochemical vinylic C–H annulation of acrylamides with alkynes

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