Enantioselective semireduction of allenes

Enantioselective semireduction of allenes

Reduction of allenes poses several challenges in terms of chemo-, regio- and enantio-selectivity. Here, the authors report a rhodium-Josiphos catalytic system that reduces a variety of aryl allenes to chiral benzylic compounds with excellent selectivity and functional group tolerance.

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Autores principales: Zhiwei Chen, Vy M. Dong
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Science
Q
Acceso en línea:https://doaj.org/article/159931391c4b4282a5960d5fa67ad034
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spelling oai:doaj.org-article:159931391c4b4282a5960d5fa67ad0342021-12-02T15:37:06ZEnantioselective semireduction of allenes10.1038/s41467-017-00793-02041-1723https://doaj.org/article/159931391c4b4282a5960d5fa67ad0342017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00793-0https://doaj.org/toc/2041-1723Reduction of allenes poses several challenges in terms of chemo-, regio- and enantio-selectivity. Here, the authors report a rhodium-Josiphos catalytic system that reduces a variety of aryl allenes to chiral benzylic compounds with excellent selectivity and functional group tolerance.Zhiwei ChenVy M. DongNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Zhiwei Chen
Vy M. Dong
Enantioselective semireduction of allenes
description Reduction of allenes poses several challenges in terms of chemo-, regio- and enantio-selectivity. Here, the authors report a rhodium-Josiphos catalytic system that reduces a variety of aryl allenes to chiral benzylic compounds with excellent selectivity and functional group tolerance.
format article
author Zhiwei Chen
Vy M. Dong
author_facet Zhiwei Chen
Vy M. Dong
author_sort Zhiwei Chen
title Enantioselective semireduction of allenes
title_short Enantioselective semireduction of allenes
title_full Enantioselective semireduction of allenes
title_fullStr Enantioselective semireduction of allenes
title_full_unstemmed Enantioselective semireduction of allenes
title_sort enantioselective semireduction of allenes
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/159931391c4b4282a5960d5fa67ad034
work_keys_str_mv AT zhiweichen enantioselectivesemireductionofallenes
AT vymdong enantioselectivesemireductionofallenes
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