Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries

Mn dissolution is dominantly responsible for capacity fading of most Mn-rich cathodes. Here the authors reveal that soluble Mn2+ species significantly destabilizes solvent and anion via its unique solvation sheath structure, providing insight into the failure mechanism of related cathode chemistries...

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Autores principales: Cun Wang, Lidan Xing, Jenel Vatamanu, Zhi Chen, Guangyuan Lan, Weishan Li, Kang Xu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/15b6ca59c9534980b2f6da17ffc706c2
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spelling oai:doaj.org-article:15b6ca59c9534980b2f6da17ffc706c22021-12-02T16:57:23ZOverlooked electrolyte destabilization by manganese (II) in lithium-ion batteries10.1038/s41467-019-11439-82041-1723https://doaj.org/article/15b6ca59c9534980b2f6da17ffc706c22019-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11439-8https://doaj.org/toc/2041-1723Mn dissolution is dominantly responsible for capacity fading of most Mn-rich cathodes. Here the authors reveal that soluble Mn2+ species significantly destabilizes solvent and anion via its unique solvation sheath structure, providing insight into the failure mechanism of related cathode chemistries.Cun WangLidan XingJenel VatamanuZhi ChenGuangyuan LanWeishan LiKang XuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Cun Wang
Lidan Xing
Jenel Vatamanu
Zhi Chen
Guangyuan Lan
Weishan Li
Kang Xu
Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries
description Mn dissolution is dominantly responsible for capacity fading of most Mn-rich cathodes. Here the authors reveal that soluble Mn2+ species significantly destabilizes solvent and anion via its unique solvation sheath structure, providing insight into the failure mechanism of related cathode chemistries.
format article
author Cun Wang
Lidan Xing
Jenel Vatamanu
Zhi Chen
Guangyuan Lan
Weishan Li
Kang Xu
author_facet Cun Wang
Lidan Xing
Jenel Vatamanu
Zhi Chen
Guangyuan Lan
Weishan Li
Kang Xu
author_sort Cun Wang
title Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries
title_short Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries
title_full Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries
title_fullStr Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries
title_full_unstemmed Overlooked electrolyte destabilization by manganese (II) in lithium-ion batteries
title_sort overlooked electrolyte destabilization by manganese (ii) in lithium-ion batteries
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/15b6ca59c9534980b2f6da17ffc706c2
work_keys_str_mv AT cunwang overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
AT lidanxing overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
AT jenelvatamanu overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
AT zhichen overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
AT guangyuanlan overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
AT weishanli overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
AT kangxu overlookedelectrolytedestabilizationbymanganeseiiinlithiumionbatteries
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