SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS

Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowin...

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Autores principales:	MODOU SARR, AMINATA DIASSE-SARR, LIBASSE DIOP
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2020
Materias:	bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/15c8ced0c1e8417ea3c21b6c805a7f57
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spelling	oai:doaj.org-article:15c8ced0c1e8417ea3c21b6c805a7f572021-12-02T19:50:32ZSYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS10.29081/jesr.v6i1.2012068-75592344-4932https://doaj.org/article/15c8ced0c1e8417ea3c21b6c805a7f572020-07-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/201https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and triple metallic components or of infinite chain types, the anion behaving as a monochelating, a bichelating or a bidentate ligand. In OH containing structures, when extra hydrogen bonds are considered, supramolecular architectures may be obtained. MODOU SARRAMINATA DIASSE-SARRLIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlebidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architecturesTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 6, Iss 1 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures Technology T Engineering (General). Civil engineering (General) TA1-2040 MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
description	Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and triple metallic components or of infinite chain types, the anion behaving as a monochelating, a bichelating or a bidentate ligand. In OH containing structures, when extra hydrogen bonds are considered, supramolecular architectures may be obtained.
format	article
author	MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP
author_facet	MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP
author_sort	MODOU SARR
title	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_short	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_full	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_fullStr	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_full_unstemmed	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_sort	synthesis and infrared study of some phenylphosphonate, diphenylphosphinate and acetatophosphonate new organotin (iv) derivatives and adducts
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2020
url	https://doaj.org/article/15c8ced0c1e8417ea3c21b6c805a7f57
work_keys_str_mv	AT modousarr synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts AT aminatadiassesarr synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts AT libassediop synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts
_version_	1718375885051002880

SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS

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