Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction

Revealing the structure and dynamics of active sites is essential to understand catalytic mechanisms. Here the authors demonstrate the dynamic nature of perimeter Pt0−O vacancy−Ce3+ sites in Pt/CeO2 and the key effects of their dynamics on the mechanism of the water gas shift reaction.

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Detalles Bibliográficos
Autores principales: Yuanyuan Li, Matthew Kottwitz, Joshua L. Vincent, Michael J. Enright, Zongyuan Liu, Lihua Zhang, Jiahao Huang, Sanjaya D. Senanayake, Wei-Chang D. Yang, Peter A. Crozier, Ralph G. Nuzzo, Anatoly I. Frenkel
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/162febbfa3814d3abbe2585eb3a7b085
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Sumario:Revealing the structure and dynamics of active sites is essential to understand catalytic mechanisms. Here the authors demonstrate the dynamic nature of perimeter Pt0−O vacancy−Ce3+ sites in Pt/CeO2 and the key effects of their dynamics on the mechanism of the water gas shift reaction.