Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction

Revealing the structure and dynamics of active sites is essential to understand catalytic mechanisms. Here the authors demonstrate the dynamic nature of perimeter Pt0−O vacancy−Ce3+ sites in Pt/CeO2 and the key effects of their dynamics on the mechanism of the water gas shift reaction.

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Autores principales: Yuanyuan Li, Matthew Kottwitz, Joshua L. Vincent, Michael J. Enright, Zongyuan Liu, Lihua Zhang, Jiahao Huang, Sanjaya D. Senanayake, Wei-Chang D. Yang, Peter A. Crozier, Ralph G. Nuzzo, Anatoly I. Frenkel
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/162febbfa3814d3abbe2585eb3a7b085
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spelling oai:doaj.org-article:162febbfa3814d3abbe2585eb3a7b0852021-12-02T13:30:07ZDynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction10.1038/s41467-021-21132-42041-1723https://doaj.org/article/162febbfa3814d3abbe2585eb3a7b0852021-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21132-4https://doaj.org/toc/2041-1723Revealing the structure and dynamics of active sites is essential to understand catalytic mechanisms. Here the authors demonstrate the dynamic nature of perimeter Pt0−O vacancy−Ce3+ sites in Pt/CeO2 and the key effects of their dynamics on the mechanism of the water gas shift reaction.Yuanyuan LiMatthew KottwitzJoshua L. VincentMichael J. EnrightZongyuan LiuLihua ZhangJiahao HuangSanjaya D. SenanayakeWei-Chang D. YangPeter A. CrozierRalph G. NuzzoAnatoly I. FrenkelNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yuanyuan Li
Matthew Kottwitz
Joshua L. Vincent
Michael J. Enright
Zongyuan Liu
Lihua Zhang
Jiahao Huang
Sanjaya D. Senanayake
Wei-Chang D. Yang
Peter A. Crozier
Ralph G. Nuzzo
Anatoly I. Frenkel
Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
description Revealing the structure and dynamics of active sites is essential to understand catalytic mechanisms. Here the authors demonstrate the dynamic nature of perimeter Pt0−O vacancy−Ce3+ sites in Pt/CeO2 and the key effects of their dynamics on the mechanism of the water gas shift reaction.
format article
author Yuanyuan Li
Matthew Kottwitz
Joshua L. Vincent
Michael J. Enright
Zongyuan Liu
Lihua Zhang
Jiahao Huang
Sanjaya D. Senanayake
Wei-Chang D. Yang
Peter A. Crozier
Ralph G. Nuzzo
Anatoly I. Frenkel
author_facet Yuanyuan Li
Matthew Kottwitz
Joshua L. Vincent
Michael J. Enright
Zongyuan Liu
Lihua Zhang
Jiahao Huang
Sanjaya D. Senanayake
Wei-Chang D. Yang
Peter A. Crozier
Ralph G. Nuzzo
Anatoly I. Frenkel
author_sort Yuanyuan Li
title Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
title_short Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
title_full Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
title_fullStr Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
title_full_unstemmed Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
title_sort dynamic structure of active sites in ceria-supported pt catalysts for the water gas shift reaction
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/162febbfa3814d3abbe2585eb3a7b085
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