Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution

The oxidative degradation of Orange G dye by nanosized CeO2 catalyst has been performed in this study. The catalyst was prepared by precipitation method. Various characterization techniques were carried out to study the physical and chemical properties of the synthesized catalyst. The XRD result co...

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Autor principal: Atheel Alwash
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Lenguaje:EN
Publicado: Al-Khwarizmi College of Engineering – University of Baghdad 2017
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Acceso en línea:https://doaj.org/article/16542ce7e1054a149dcb86072eb3d2f7
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spelling oai:doaj.org-article:16542ce7e1054a149dcb86072eb3d2f72021-12-02T05:46:59ZStudy the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution10.22153/kej.2017.09.0021818-11712312-0789https://doaj.org/article/16542ce7e1054a149dcb86072eb3d2f72017-03-01T00:00:00Zhttp://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/339https://doaj.org/toc/1818-1171https://doaj.org/toc/2312-0789 The oxidative degradation of Orange G dye by nanosized CeO2 catalyst has been performed in this study. The catalyst was prepared by precipitation method. Various characterization techniques were carried out to study the physical and chemical properties of the synthesized catalyst. The XRD result confirms well the formation of CeO2 cubic phase.  The FTIR result showed the effect of calcination temperature for CeO2 was clearly observed due to reduction in band intensity compared to uncalcined Ce nitrate sample. Meanwhile, the diffused reflection spectra recorded reflection spectra at 414 nm with an energy gap of 3.2 ev. The decolorization of Orange G dye by oxidation process were carried out  under various conditions such as,  the  effects  of  H2O2 dosage ,  pH, catalyst dosage  and  the  temperature of reaction. The optimum conditions for the highest decolorization efficiency (100%) were achieved at 10 mg/L of orange G  dye with catalyst  dosage of 1.5 g/L, pH 2, reaction temperature of 65 °C and 0.1 mL H2O2. Atheel AlwashAl-Khwarizmi College of Engineering – University of BaghdadarticleCerium oxideOxidation processNanoparticlesHeterogeneous catalystChemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 13, Iss 1 (2017)
institution DOAJ
collection DOAJ
language EN
topic Cerium oxide
Oxidation process
Nanoparticles
Heterogeneous catalyst
Chemical engineering
TP155-156
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle Cerium oxide
Oxidation process
Nanoparticles
Heterogeneous catalyst
Chemical engineering
TP155-156
Engineering (General). Civil engineering (General)
TA1-2040
Atheel Alwash
Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution
description The oxidative degradation of Orange G dye by nanosized CeO2 catalyst has been performed in this study. The catalyst was prepared by precipitation method. Various characterization techniques were carried out to study the physical and chemical properties of the synthesized catalyst. The XRD result confirms well the formation of CeO2 cubic phase.  The FTIR result showed the effect of calcination temperature for CeO2 was clearly observed due to reduction in band intensity compared to uncalcined Ce nitrate sample. Meanwhile, the diffused reflection spectra recorded reflection spectra at 414 nm with an energy gap of 3.2 ev. The decolorization of Orange G dye by oxidation process were carried out  under various conditions such as,  the  effects  of  H2O2 dosage ,  pH, catalyst dosage  and  the  temperature of reaction. The optimum conditions for the highest decolorization efficiency (100%) were achieved at 10 mg/L of orange G  dye with catalyst  dosage of 1.5 g/L, pH 2, reaction temperature of 65 °C and 0.1 mL H2O2.
format article
author Atheel Alwash
author_facet Atheel Alwash
author_sort Atheel Alwash
title Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution
title_short Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution
title_full Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution
title_fullStr Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution
title_full_unstemmed Study the Catalytic Activity of CeO2 Catalyst for the Oxidative Degradation of Orange G Dye in Aqueous Solution
title_sort study the catalytic activity of ceo2 catalyst for the oxidative degradation of orange g dye in aqueous solution
publisher Al-Khwarizmi College of Engineering – University of Baghdad
publishDate 2017
url https://doaj.org/article/16542ce7e1054a149dcb86072eb3d2f7
work_keys_str_mv AT atheelalwash studythecatalyticactivityofceo2catalystfortheoxidativedegradationoforangegdyeinaqueoussolution
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