Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater

Precipitation dechlorination has the advantage of being a simple process with a low cost. However, there are few reports on the effect of cations on dechlorination. In this study, we investigated the effect of cations in high-salt wastewater on the removal of chlorine ions by cuprous chloride precip...

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Autores principales: Kangning Gao, Jie Lu, Xi Wang, Dengxin Li, Shihong Xu
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Publicado: IWA Publishing 2021
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spelling oai:doaj.org-article:16c7cba09b094ef1a4b1cfee0dab30832021-11-06T11:01:52ZEffect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater0273-12231996-973210.2166/wst.2021.098https://doaj.org/article/16c7cba09b094ef1a4b1cfee0dab30832021-05-01T00:00:00Zhttp://wst.iwaponline.com/content/83/9/2232https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732Precipitation dechlorination has the advantage of being a simple process with a low cost. However, there are few reports on the effect of cations on dechlorination. In this study, we investigated the effect of cations in high-salt wastewater on the removal of chlorine ions by cuprous chloride precipitation and analysed the corresponding mechanism. A series of investigations revealed that Fe3+ could oxidise sulphite, thereby reducing the removal rate of chlorine ions. The reaction between magnesium and sulphite results in precipitation, which has a slightly adverse effect on the removal of chloride ions. Hexavalent chromium oxidises the chloride ion, resulting in the formation of chlorine gas, which improves the removal rate. Ferrous and manganese, however, do not have a notable effect on chlorine removal. HIGHLIGHTS This paper describes the effect of cations in high-salt wastewater on the removal of chlorine ions by cuprous chloride precipitation.; Fe3+ can be converted to Fe2+ to reduce the inhibitory effect on chloride ion removal.; Chromium oxidises the chloride ion, which improves the removal rate.; The removal of chloride ions from high-salt wastewater via the cuprous chloride precipitation method is economical.;Kangning GaoJie LuXi WangDengxin LiShihong XuIWA Publishingarticlecationchloride ionhigh-salt wastewatermechanismprecipitationEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 9, Pp 2232-2241 (2021)
institution DOAJ
collection DOAJ
language EN
topic cation
chloride ion
high-salt wastewater
mechanism
precipitation
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle cation
chloride ion
high-salt wastewater
mechanism
precipitation
Environmental technology. Sanitary engineering
TD1-1066
Kangning Gao
Jie Lu
Xi Wang
Dengxin Li
Shihong Xu
Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
description Precipitation dechlorination has the advantage of being a simple process with a low cost. However, there are few reports on the effect of cations on dechlorination. In this study, we investigated the effect of cations in high-salt wastewater on the removal of chlorine ions by cuprous chloride precipitation and analysed the corresponding mechanism. A series of investigations revealed that Fe3+ could oxidise sulphite, thereby reducing the removal rate of chlorine ions. The reaction between magnesium and sulphite results in precipitation, which has a slightly adverse effect on the removal of chloride ions. Hexavalent chromium oxidises the chloride ion, resulting in the formation of chlorine gas, which improves the removal rate. Ferrous and manganese, however, do not have a notable effect on chlorine removal. HIGHLIGHTS This paper describes the effect of cations in high-salt wastewater on the removal of chlorine ions by cuprous chloride precipitation.; Fe3+ can be converted to Fe2+ to reduce the inhibitory effect on chloride ion removal.; Chromium oxidises the chloride ion, which improves the removal rate.; The removal of chloride ions from high-salt wastewater via the cuprous chloride precipitation method is economical.;
format article
author Kangning Gao
Jie Lu
Xi Wang
Dengxin Li
Shihong Xu
author_facet Kangning Gao
Jie Lu
Xi Wang
Dengxin Li
Shihong Xu
author_sort Kangning Gao
title Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
title_short Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
title_full Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
title_fullStr Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
title_full_unstemmed Effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
title_sort effect of cations on the removal rate of chloride ions and mechanism analysis in high-salt wastewater
publisher IWA Publishing
publishDate 2021
url https://doaj.org/article/16c7cba09b094ef1a4b1cfee0dab3083
work_keys_str_mv AT kangninggao effectofcationsontheremovalrateofchlorideionsandmechanismanalysisinhighsaltwastewater
AT jielu effectofcationsontheremovalrateofchlorideionsandmechanismanalysisinhighsaltwastewater
AT xiwang effectofcationsontheremovalrateofchlorideionsandmechanismanalysisinhighsaltwastewater
AT dengxinli effectofcationsontheremovalrateofchlorideionsandmechanismanalysisinhighsaltwastewater
AT shihongxu effectofcationsontheremovalrateofchlorideionsandmechanismanalysisinhighsaltwastewater
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