Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy

Glycosyl cations are key intermediates in glycosylation reactions, but their structure has remained elusive due to their transient nature. Here, the authors perform an in-depth structural analysis and report that C2-participating protective groups induce acetoxonium cations with distinct ring confor...

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Autores principales:	Eike Mucha, Mateusz Marianski, Fei-Fei Xu, Daniel A. Thomas, Gerard Meijer, Gert von Helden, Peter H. Seeberger, Kevin Pagel
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/16eaf90c51474dba898e1bed4960c53d
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spelling	oai:doaj.org-article:16eaf90c51474dba898e1bed4960c53d2021-12-02T16:49:19ZUnravelling the structure of glycosyl cations via cold-ion infrared spectroscopy10.1038/s41467-018-06764-32041-1723https://doaj.org/article/16eaf90c51474dba898e1bed4960c53d2018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06764-3https://doaj.org/toc/2041-1723Glycosyl cations are key intermediates in glycosylation reactions, but their structure has remained elusive due to their transient nature. Here, the authors perform an in-depth structural analysis and report that C2-participating protective groups induce acetoxonium cations with distinct ring conformations.Eike MuchaMateusz MarianskiFei-Fei XuDaniel A. ThomasGerard MeijerGert von HeldenPeter H. SeebergerKevin PagelNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-5 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Eike Mucha Mateusz Marianski Fei-Fei Xu Daniel A. Thomas Gerard Meijer Gert von Helden Peter H. Seeberger Kevin Pagel Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
description	Glycosyl cations are key intermediates in glycosylation reactions, but their structure has remained elusive due to their transient nature. Here, the authors perform an in-depth structural analysis and report that C2-participating protective groups induce acetoxonium cations with distinct ring conformations.
format	article
author	Eike Mucha Mateusz Marianski Fei-Fei Xu Daniel A. Thomas Gerard Meijer Gert von Helden Peter H. Seeberger Kevin Pagel
author_facet	Eike Mucha Mateusz Marianski Fei-Fei Xu Daniel A. Thomas Gerard Meijer Gert von Helden Peter H. Seeberger Kevin Pagel
author_sort	Eike Mucha
title	Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
title_short	Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
title_full	Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
title_fullStr	Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
title_full_unstemmed	Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
title_sort	unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/16eaf90c51474dba898e1bed4960c53d
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Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy

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