Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy

Unravelling the structure of glycosyl cations via cold-ion infrared spectroscopy

Glycosyl cations are key intermediates in glycosylation reactions, but their structure has remained elusive due to their transient nature. Here, the authors perform an in-depth structural analysis and report that C2-participating protective groups induce acetoxonium cations with distinct ring confor...

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Autores principales: Eike Mucha, Mateusz Marianski, Fei-Fei Xu, Daniel A. Thomas, Gerard Meijer, Gert von Helden, Peter H. Seeberger, Kevin Pagel
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Science
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Acceso en línea:https://doaj.org/article/16eaf90c51474dba898e1bed4960c53d
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