Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures

Photochemistry in solution often involves coexisting reaction channels that may comprise intermediates capturing a solvent molecule. Here, the authors show for one of the most reactive species, diphenylcarbene, that the decision-maker is not the nearest solvent molecule but its neighbour.

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Autores principales:	Johannes Knorr, Pandian Sokkar, Sebastian Schott, Paolo Costa, Walter Thiel, Wolfram Sander, Elsa Sanchez-Garcia, Patrick Nuernberger
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/17e094751c9942fd81e8bc9b4933799c
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spelling	oai:doaj.org-article:17e094751c9942fd81e8bc9b4933799c2021-12-02T14:40:14ZCompetitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures10.1038/ncomms129682041-1723https://doaj.org/article/17e094751c9942fd81e8bc9b4933799c2016-10-01T00:00:00Zhttps://doi.org/10.1038/ncomms12968https://doaj.org/toc/2041-1723Photochemistry in solution often involves coexisting reaction channels that may comprise intermediates capturing a solvent molecule. Here, the authors show for one of the most reactive species, diphenylcarbene, that the decision-maker is not the nearest solvent molecule but its neighbour.Johannes KnorrPandian SokkarSebastian SchottPaolo CostaWalter ThielWolfram SanderElsa Sanchez-GarciaPatrick NuernbergerNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Johannes Knorr Pandian Sokkar Sebastian Schott Paolo Costa Walter Thiel Wolfram Sander Elsa Sanchez-Garcia Patrick Nuernberger Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
description	Photochemistry in solution often involves coexisting reaction channels that may comprise intermediates capturing a solvent molecule. Here, the authors show for one of the most reactive species, diphenylcarbene, that the decision-maker is not the nearest solvent molecule but its neighbour.
format	article
author	Johannes Knorr Pandian Sokkar Sebastian Schott Paolo Costa Walter Thiel Wolfram Sander Elsa Sanchez-Garcia Patrick Nuernberger
author_facet	Johannes Knorr Pandian Sokkar Sebastian Schott Paolo Costa Walter Thiel Wolfram Sander Elsa Sanchez-Garcia Patrick Nuernberger
author_sort	Johannes Knorr
title	Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
title_short	Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
title_full	Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
title_fullStr	Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
title_full_unstemmed	Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
title_sort	competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/17e094751c9942fd81e8bc9b4933799c
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Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures

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