Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
Photochemistry in solution often involves coexisting reaction channels that may comprise intermediates capturing a solvent molecule. Here, the authors show for one of the most reactive species, diphenylcarbene, that the decision-maker is not the nearest solvent molecule but its neighbour.
Guardado en:
Autores principales: | Johannes Knorr, Pandian Sokkar, Sebastian Schott, Paolo Costa, Walter Thiel, Wolfram Sander, Elsa Sanchez-Garcia, Patrick Nuernberger |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2016
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Materias: | |
Acceso en línea: | https://doaj.org/article/17e094751c9942fd81e8bc9b4933799c |
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